{"id":"W2952234416","doi":"10.1139/v00-126","title":"1999 R.U. Lemieux Award Lecture Adventures with azo-, azoxy-, and hydrazoarenes: from the Wallach to the benzidine rearrangement. Molecular electronics","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Benzidine; Azoxy; Molecule; Transition state; Catalysis; Stereochemistry; Photochemistry; Medicinal chemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001291041,0.0006836092,0.0003058699,0.0007359701,0.0006005372,0.001824421,0.0005811332,0.001793322,0.03958919],"category_scores_gemma":[0.0009562519,0.0002506024,0.0003017109,0.0004082061,0.0007460233,0.001952985,0.001029892,0.002294781,0.0126624],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001583886,"about_ca_system_score_gemma":0.0008272944,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007040818,"about_ca_topic_score_gemma":0.001939116,"domain_scores_codex":[0.999535,0.00006404206,0.0000207131,0.0001285091,0.0001618931,0.00008983831],"domain_scores_gemma":[0.9992949,0.0001392768,0.00003297154,0.00002419188,0.0001782516,0.0003304143],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004747221,0.0001820895,0.001079948,0.0003423643,0.00003332696,0.0006818746,0.0004231743,0.0004358528,0.009843105,0.03742292,0.6561132,0.2929674],"study_design_scores_gemma":[0.00001422209,0.0001927487,0.0008133348,0.0001230619,0.000009081093,0.0005176504,0.0001692121,0.0003244944,0.003724382,0.003448061,0.9906474,0.00001634944],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.02972206,0.2077045,0.01625728,0.2427915,0.07599004,0.000208285,0.0004516899,0.0005455104,0.4263291],"genre_scores_gemma":[0.05160464,0.05995744,0.004239299,0.006369759,0.01484529,0.00004554506,0.0001437229,0.0001230845,0.8626713],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.03958919,"threshold_uncertainty_score":0.1324391,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003697310704705562,"score_gpt":0.1837657548519458,"score_spread":0.1800684441472403,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}