{"id":"W2952235482","doi":"10.1016/s0040-4020(01)00422-7","title":"Metal mediated carbometallation of alkynes and alkenes containing adjacent heteroatoms","year":2001,"lang":"en","type":"article","venue":"Tetrahedron","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":169,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Heteroatom; Metal; Stereochemistry; Combinatorial chemistry; Organic chemistry; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001736794,0.0005098585,0.0002621128,0.0002966817,0.0003599689,0.0002467064,0.0006298408,0.0004166855,0.002276087],"category_scores_gemma":[0.0002010931,0.0001936503,0.0002200702,0.0002521514,0.000288272,0.00030741,0.0003577868,0.000476634,0.0005184418],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005203699,"about_ca_system_score_gemma":0.0002966741,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002228172,"about_ca_topic_score_gemma":0.005009769,"domain_scores_codex":[0.9998461,0.00001621939,0.000007853155,0.00003045949,0.00003083485,0.00006846871],"domain_scores_gemma":[0.999952,0.00001082076,0.00001148183,0.00001012866,0.000005193946,0.00001037305],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006558414,0.0001170121,0.0002324556,0.0004116377,0.000037944,0.0007825842,0.0002909921,0.0009676103,0.9735886,0.006606267,0.00161758,0.01469148],"study_design_scores_gemma":[0.00009076251,0.000384757,0.0009024056,0.0000130472,0.00002227105,0.0002772998,0.00003832147,0.0009619103,0.9890872,0.0003807334,0.007822454,0.0000187922],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9553295,0.002679465,0.006269268,0.0002511912,0.0001993745,0.0001012882,0.0003067187,0.0002931862,0.03456996],"genre_scores_gemma":[0.9924084,0.0007980885,0.001344424,0.00004976578,0.0000182947,0.00001955831,0.0001464504,0.00002340948,0.005191605],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002276087,"threshold_uncertainty_score":0.007614315,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02789062425730773,"score_gpt":0.2798519851642123,"score_spread":0.2519613609069046,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}