{"id":"W2952254816","doi":"10.1002/chin.201538051","title":"ChemInform Abstract: A Transition‐Metal‐Free Heck‐Type Reaction Between Alkenes and Alkyl Iodides Enabled by Light in Water.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Alkyl; Aqueous solution; Transition metal; Photochemistry; Irradiation; Aqueous medium; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003423678,0.0003678501,0.0004394819,0.0001210232,0.0001210172,0.0001536487,0.0003068844,0.0003913619,0.0004054005],"category_scores_gemma":[0.0002138088,0.0003330375,0.0001014333,0.0002233379,0.0001434706,0.0008575072,0.0001153327,0.000432275,0.0001161513],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004320731,"about_ca_system_score_gemma":0.0001207199,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004626969,"about_ca_topic_score_gemma":0.00005533258,"domain_scores_codex":[0.9979914,1.64598e-8,0.000668153,0.0003881559,0.0003916172,0.0005606636],"domain_scores_gemma":[0.9986244,0.00008616877,0.0001608989,0.0006335263,0.0001709388,0.0003240664],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001272579,0.0001070545,0.0002879958,0.0003195361,0.00008447481,0.00001243116,0.00365159,8.637321e-7,0.9463465,0.000007924064,0.02024619,0.02880821],"study_design_scores_gemma":[0.001549274,0.00001957338,0.0002224411,0.0000880626,0.00007086802,0.0000683624,0.001150238,0.00001334301,0.9170669,0.0002308086,0.07911845,0.000401693],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8423105,0.0002156628,1.043853e-7,0.0004809722,0.0001026603,0.0001285463,0.00007537731,0.0001870092,0.1564991],"genre_scores_gemma":[0.9812121,0.0000706442,0.000006803858,0.00004561088,0.000251754,0.00004473934,0.00132407,0.00004611531,0.0169981],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.139501,"threshold_uncertainty_score":0.9999121,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01999702826304116,"score_gpt":0.2509979804555216,"score_spread":0.2310009521924804,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}