{"id":"W2952254816","doi":"10.1002/chin.201538051","title":"ChemInform Abstract: A Transition‐Metal‐Free Heck‐Type Reaction Between Alkenes and Alkyl Iodides Enabled by Light in Water.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Alkyl; Aqueous solution; Transition metal; Photochemistry; Irradiation; Aqueous medium; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002211339,0.0006189541,0.0001310423,0.0003933671,0.0003068796,0.0003372335,0.0005223632,0.0003838935,0.01167518],"category_scores_gemma":[0.0001981237,0.0002542158,0.0001725102,0.0003323532,0.0002963894,0.0006147578,0.0004946679,0.0006217153,0.002324529],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004546491,"about_ca_system_score_gemma":0.000544725,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007221805,"about_ca_topic_score_gemma":0.001815126,"domain_scores_codex":[0.9998757,0.0000137643,0.000006119089,0.0000286562,0.0000406,0.00003520574],"domain_scores_gemma":[0.9999464,0.00001237116,0.00001206642,0.000007576212,0.000009091429,0.00001261501],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004319467,0.00009773886,0.0002706982,0.0007457876,0.00005073469,0.0004089222,0.0002141852,0.0003777086,0.9688213,0.005283073,0.004160917,0.019137],"study_design_scores_gemma":[0.00003494788,0.0001418189,0.0003596119,0.00001646458,0.00002716671,0.0001977503,0.00002076203,0.0002738664,0.9845867,0.0001565473,0.01417257,0.00001180925],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7391783,0.008020926,0.03467718,0.0009802746,0.0005424645,0.0003139648,0.002381153,0.002469129,0.2114366],"genre_scores_gemma":[0.9624563,0.002354937,0.004504964,0.0001614023,0.00003856977,0.00004656114,0.0009559644,0.00009495727,0.02938624],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01167518,"threshold_uncertainty_score":0.03905737,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01999702826304116,"score_gpt":0.2509979804555216,"score_spread":0.2310009521924804,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}