{"id":"W2952313669","doi":"10.1002/chin.201006235","title":"ChemInform Abstract: Hydroxylamine, Oximate and Hydroxamate as α‐Nucleophiles in Dephosphorylation","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Hydroxylamine; Dephosphorylation; Nucleophile; Combinatorial chemistry; Service (business); Medicinal chemistry; Organic chemistry; Business; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003691681,0.0007613947,0.0002813645,0.0003153458,0.0001979538,0.0003076601,0.0004162772,0.000359114,0.01511272],"category_scores_gemma":[0.0002357588,0.0002472473,0.000234479,0.0002504357,0.0002183513,0.0006932446,0.0004192051,0.0006869163,0.004169393],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002556489,"about_ca_system_score_gemma":0.0003513428,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000292822,"about_ca_topic_score_gemma":0.0003504665,"domain_scores_codex":[0.9998628,0.00002231765,0.0000130688,0.00002624048,0.00003680566,0.00003866684],"domain_scores_gemma":[0.9999362,0.00001358138,0.00001595855,0.000007794326,0.00001024367,0.00001623167],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001619388,0.000127369,0.0001774021,0.001474333,0.00004893096,0.0006130002,0.0001455884,0.001035153,0.896638,0.006291116,0.0101734,0.08165637],"study_design_scores_gemma":[0.0001059465,0.0006732992,0.0003806369,0.00004414284,0.00003955535,0.0003487292,0.00001509355,0.0006027874,0.9607118,0.0006060704,0.03645576,0.00001616361],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6480335,0.04621233,0.09916631,0.002392201,0.002946865,0.0006714134,0.005122136,0.00271437,0.192741],"genre_scores_gemma":[0.9032144,0.02086012,0.01295541,0.0004513931,0.0004047279,0.000130142,0.001938882,0.0002733207,0.05977159],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01511272,"threshold_uncertainty_score":0.05055714,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00563098698022773,"score_gpt":0.2088819340060327,"score_spread":0.203250947025805,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}