{"id":"W2952369933","doi":"10.1021/ja010837+","title":"Stability, Reactivity, Solution, and Solid-State Structure of Halomethylzinc Alkoxides","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Chemistry; Reactivity (psychology); Lewis acids and bases; Intramolecular force; Allylic rearrangement; Catalysis; Zinc; Enantioselective synthesis; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001959904,0.0001691678,0.0004607261,0.00001581891,0.00007733457,0.00002071473,0.000338499,0.00007600823,0.00008717101],"category_scores_gemma":[0.0002015067,0.0001170096,0.0004176533,0.0002677363,0.0005857814,0.0001257311,0.0002181972,0.0006082872,3.75283e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000252485,"about_ca_system_score_gemma":0.00009780718,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009691253,"about_ca_topic_score_gemma":0.000005144459,"domain_scores_codex":[0.9985965,0.00003863733,0.0004778671,0.0001750693,0.0004766998,0.0002352399],"domain_scores_gemma":[0.9979624,0.0001825033,0.001175468,0.0003030039,0.0002530519,0.0001235399],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007783475,0.00007002224,0.00582837,0.00006129782,0.0001034217,0.000001592867,0.0005650677,0.000006052222,0.9867477,0.000003910682,0.0002261308,0.006308638],"study_design_scores_gemma":[0.0003447492,0.00003300511,0.001598852,0.00004045003,0.00007280611,0.00032323,0.001241408,0.00004826023,0.993708,0.001481719,0.0009847885,0.0001227577],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986371,0.0001517111,0.0002346003,0.0006890624,0.00006137923,0.00003724175,0.00002057795,0.00001437325,0.0001539013],"genre_scores_gemma":[0.9966744,0.0003461892,0.002646907,0.0001151342,0.0001593716,5.389451e-7,0.000001088993,0.00002013543,0.00003620453],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006960313,"threshold_uncertainty_score":0.4771514,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01214057036980886,"score_gpt":0.2597233348276884,"score_spread":0.2475827644578796,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}