{"id":"W2952372258","doi":"10.1002/chin.200742031","title":"Synthesis of a New Chiral Amino Phosphine Ligand (TIQN) and Its Application in the Asymmetric Allylic Alkylation (AAA) Reaction.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Tsuji–Trost reaction; Phosphine; Allylic rearrangement; Ligand (biochemistry); Alkylation; Combinatorial chemistry; Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001514144,0.0002755225,0.0001958227,0.0001784141,0.0002285714,0.0002213906,0.0004321717,0.0003337614,0.002856866],"category_scores_gemma":[0.0001703368,0.0001388362,0.0001787082,0.000216355,0.000179264,0.0003703825,0.0003433617,0.0005444955,0.00120048],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000388542,"about_ca_system_score_gemma":0.0005332215,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001052949,"about_ca_topic_score_gemma":0.001454706,"domain_scores_codex":[0.9999435,0.000007858723,0.000004490654,0.00001422149,0.00001555928,0.00001421986],"domain_scores_gemma":[0.9999691,0.00000411161,0.000005576895,0.000003788162,0.000004552875,0.00001288806],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001562368,0.0001204062,0.0000976041,0.0004133655,0.00001535832,0.000530782,0.0001041205,0.001538022,0.9598942,0.003556532,0.001647773,0.03192557],"study_design_scores_gemma":[0.0001051091,0.0008326422,0.0003696457,0.00002728694,0.00002591748,0.001108693,0.00003279561,0.00400692,0.9556817,0.0006985021,0.03707714,0.00003366212],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7692033,0.01111639,0.1531549,0.001592479,0.0006683966,0.0006325573,0.001620534,0.001479918,0.06053156],"genre_scores_gemma":[0.9155384,0.005880067,0.05310147,0.0003759112,0.00006010175,0.0001846021,0.001131268,0.0001125447,0.02361557],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002856866,"threshold_uncertainty_score":0.009557188,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01056528707635178,"score_gpt":0.231251739101848,"score_spread":0.2206864520254962,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}