{"id":"W2952385110","doi":"10.1002/chin.201108112","title":"ChemInform Abstract: 2‐Substituted Benzo[b]furans from (E)‐1,2‐Dichlorovinyl Ethers and Organoboron Reagents: Scope and Mechanistic Investigations into the One‐Pot Suzuki Coupling/Direct Arylation.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Chemistry; Reagent; Suzuki reaction; Organoboron compounds; Scope (computer science); Coupling (piping); Organic chemistry; Combinatorial chemistry; Computational chemistry; Medicinal chemistry; Stereochemistry; Palladium; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001537425,0.0005533255,0.0001150314,0.0002766876,0.0002396665,0.0002147921,0.0002477119,0.0002177675,0.006968938],"category_scores_gemma":[0.0001256575,0.0001922194,0.0001341182,0.0002203411,0.0001813628,0.0002798628,0.0002473602,0.0003746474,0.001571445],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003405784,"about_ca_system_score_gemma":0.0003640644,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008944874,"about_ca_topic_score_gemma":0.002445074,"domain_scores_codex":[0.9999105,0.00001302597,0.000004047837,0.00001504608,0.00002724109,0.00003013241],"domain_scores_gemma":[0.9999654,0.000006805979,0.00000914305,0.000004068917,0.000006758644,0.000007733572],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003092721,0.00006643406,0.0002795099,0.0002616414,0.00002390263,0.000239888,0.00007705715,0.0004594113,0.978873,0.002231098,0.001037951,0.01614079],"study_design_scores_gemma":[0.00003810186,0.0001947227,0.000923755,0.00001085052,0.00001644758,0.0002156922,0.00001489605,0.0002321464,0.9868727,0.0001055734,0.01136742,0.000007695029],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8623638,0.006804857,0.01909216,0.0003943816,0.0001125378,0.0001895468,0.002217842,0.000550258,0.1082746],"genre_scores_gemma":[0.9770783,0.003348642,0.004683335,0.00009385837,0.00002451757,0.00005415832,0.001409756,0.0000375969,0.01326981],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006968938,"threshold_uncertainty_score":0.02331346,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03004781307530902,"score_gpt":0.2401187383265599,"score_spread":0.2100709252512509,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}