{"id":"W2952385110","doi":"10.1002/chin.201108112","title":"ChemInform Abstract: 2‐Substituted Benzo[b]furans from (E)‐1,2‐Dichlorovinyl Ethers and Organoboron Reagents: Scope and Mechanistic Investigations into the One‐Pot Suzuki Coupling/Direct Arylation.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Chemistry; Reagent; Suzuki reaction; Organoboron compounds; Scope (computer science); Coupling (piping); Organic chemistry; Combinatorial chemistry; Computational chemistry; Medicinal chemistry; Stereochemistry; Palladium; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002714955,0.0004322341,0.0003774259,0.00008377399,0.0006325366,0.0002264122,0.000390419,0.0003555106,0.002242662],"category_scores_gemma":[0.0006010205,0.0003916371,0.00008935841,0.0002764185,0.0006916462,0.0006063106,0.0001868885,0.0005241855,0.00007898885],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002830196,"about_ca_system_score_gemma":0.0002450822,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003387742,"about_ca_topic_score_gemma":0.0008172579,"domain_scores_codex":[0.9979802,1.647006e-8,0.0006796684,0.0005186643,0.0003922318,0.0004291976],"domain_scores_gemma":[0.9979214,0.0003773065,0.0003717179,0.0008126288,0.0001901446,0.0003267993],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002372827,0.000326789,0.002255731,0.0007284345,0.0008271566,0.00002040293,0.04627334,0.00002298134,0.8966749,0.001348141,0.003061614,0.04822322],"study_design_scores_gemma":[0.0008166958,0.00001321671,0.003820945,0.0002342694,0.0003005308,0.00001953921,0.002346135,0.0006481855,0.9883206,0.001195716,0.00176011,0.0005240817],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9044826,0.0004787713,0.000002233019,0.0001441483,0.0001500699,0.0002622423,0.0001432227,0.0002706063,0.09406614],"genre_scores_gemma":[0.9963193,0.0003634154,0.00008037975,0.0001059793,0.0001775728,0.00007856632,0.0006859857,0.00006609855,0.002122712],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09194342,"threshold_uncertainty_score":0.9998536,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03004781307530902,"score_gpt":0.2401187383265599,"score_spread":0.2100709252512509,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}