{"id":"W2952410066","doi":"10.1002/chin.200817071","title":"ChemInform Abstract: Homoallylic Ketones and Pyrroles by Way of Copper‐Catalyzed Cascade Additions of Alkyl‐Substituted Vinyl Grignard Reagents to Esters.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Reagent; Alkyl; Cascade; Organic chemistry; Catalysis; Combinatorial chemistry; Copper; Grignard reagent","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003261745,0.001008279,0.0003100602,0.0005980066,0.0003010348,0.0004050027,0.0008980279,0.0003639167,0.01273492],"category_scores_gemma":[0.0002297898,0.0003019163,0.000350212,0.0003524,0.0003192535,0.0009436345,0.0005845075,0.0009243213,0.004609535],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005323265,"about_ca_system_score_gemma":0.0005300533,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005427623,"about_ca_topic_score_gemma":0.001107916,"domain_scores_codex":[0.9997782,0.00002738937,0.00001274797,0.00004800365,0.00004226775,0.00009135505],"domain_scores_gemma":[0.999938,0.000008719896,0.00001533949,0.00001165812,0.000008229606,0.00001806327],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000918035,0.0002922406,0.0003576401,0.00183029,0.0001310813,0.001722929,0.0005161106,0.001712739,0.8819641,0.02136609,0.01990892,0.0692798],"study_design_scores_gemma":[0.00007778467,0.0005596316,0.0005896688,0.00004615578,0.00003887433,0.000624223,0.00004310927,0.001029366,0.9685234,0.0008341651,0.02760459,0.00002901911],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6832989,0.01530469,0.06073993,0.001413441,0.002156311,0.0006682011,0.002239856,0.002797823,0.2313809],"genre_scores_gemma":[0.9359635,0.008518846,0.008772218,0.0002001805,0.0001573448,0.00009874153,0.0008545909,0.0002087267,0.04522588],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01273492,"threshold_uncertainty_score":0.04260254,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01523755023062986,"score_gpt":0.2290070209061014,"score_spread":0.2137694706754715,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}