{"id":"W2952427719","doi":"10.1021/ol9022672","title":"Stereocontrolled Access to Unsymmetrical 1,1-Diaryl-2-fluoroethenes","year":2009,"lang":"en","type":"article","venue":"Organic Letters","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Aryl; Halogenation; Combinatorial chemistry; Hydride; Coupling reaction; Reaction conditions; Suzuki reaction; Boronic acid; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004435482,0.0003652046,0.0004338218,0.0001896121,0.0001902082,0.0001000635,0.001075739,0.000307855,0.005519806],"category_scores_gemma":[0.0003891219,0.0003556802,0.0001385627,0.0009039732,0.0000828924,0.0002141755,0.000208738,0.0008541141,0.001199061],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002563065,"about_ca_system_score_gemma":0.00007137654,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008404911,"about_ca_topic_score_gemma":0.000003500118,"domain_scores_codex":[0.997734,0.0002025028,0.0004583703,0.0005706215,0.0002784304,0.0007560977],"domain_scores_gemma":[0.9983644,0.0004672325,0.0001138681,0.0004871364,0.00006310669,0.0005041966],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002567444,0.0001960972,0.002201495,0.00001053221,0.0001140068,0.0001122487,0.0001862491,0.00003189189,0.8684315,0.00007764433,0.1120824,0.01629922],"study_design_scores_gemma":[0.003321188,0.0001463903,0.006282663,0.00001024016,0.000153441,0.00007978854,0.00002571695,0.0001014082,0.915746,0.0001740359,0.07338984,0.0005693337],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9034831,0.000162497,0.0005774895,0.09126659,0.001159509,0.0005506893,0.00001542285,0.0003414016,0.002443325],"genre_scores_gemma":[0.9027318,0.00002723576,0.0002729856,0.09541882,0.0009577418,0.00002410659,0.00001241729,0.00004664834,0.0005082593],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04731445,"threshold_uncertainty_score":0.9998895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0710865702230623,"score_gpt":0.4070790013249823,"score_spread":0.33599243110192,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}