{"id":"W2952448160","doi":"10.1002/chin.201614074","title":"ChemInform Abstract: Contrasting Reactivity of CS<sub>2</sub> with Cyclic vs. Acyclic Amidines.","year":2016,"lang":"en","type":"article","venue":"ChemInform","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Reactivity (psychology); Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002273273,0.0003894001,0.000576398,0.0001544657,0.00004516335,0.00002621065,0.0003604605,0.0002442432,0.0002342963],"category_scores_gemma":[0.0008236429,0.0002880736,0.0002013427,0.0005054897,0.0001995654,0.0006503566,0.0001285868,0.000233017,0.00007833039],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003007034,"about_ca_system_score_gemma":0.00008038001,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001937139,"about_ca_topic_score_gemma":0.00001204765,"domain_scores_codex":[0.9977841,1.088664e-7,0.0007704747,0.0003610268,0.0005342244,0.0005500643],"domain_scores_gemma":[0.9978694,0.000474966,0.0005085843,0.0006941504,0.0002266996,0.0002261564],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008692698,0.0000384489,0.0004002372,0.0001659535,0.00008858085,0.000003756089,0.000138442,0.000004010476,0.8178866,0.0001011013,0.0006467634,0.1804392],"study_design_scores_gemma":[0.001153942,0.00002112323,0.002567926,0.0003024546,0.00007384095,0.00002620642,0.00006165398,0.0001004072,0.9931426,0.00002213178,0.002105978,0.0004217522],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7565774,0.00004348183,0.00006695849,0.0001084783,0.00008557054,0.0002293132,0.00005018824,0.0003416072,0.242497],"genre_scores_gemma":[0.9979158,0.0000414752,0.00003211453,0.00004190905,0.0001342623,0.00005591122,0.00006428583,0.0000655636,0.001648664],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2413385,"threshold_uncertainty_score":0.9999571,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009694887824425071,"score_gpt":0.2120906025196876,"score_spread":0.2023957146952625,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}