{"id":"W2952488158","doi":"10.1021/jo300313v","title":"Cyclic Seleninate Esters as Catalysts for the Oxidation of Sulfides to Sulfoxides, Epoxidation of Alkenes, and Conversion of Enamines to α-Hydroxyketones","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Alberta Innovates - Health Solutions","keywords":"Chemistry; Enamine; Hydrolysis; Catalysis; Styrene; Dimer; Organic chemistry; Sulfoxide; Epoxide; Oxidative cleavage; Copolymer; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002115033,0.0003140467,0.0001905519,0.0002385447,0.00009546879,0.0001869538,0.0002320652,0.0002135764,0.0009111962],"category_scores_gemma":[0.0002274431,0.000166692,0.0001694759,0.0001998152,0.00015326,0.0002804259,0.000195052,0.0003108902,0.0003767684],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001616925,"about_ca_system_score_gemma":0.0001691488,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003137229,"about_ca_topic_score_gemma":0.0009550369,"domain_scores_codex":[0.9998906,0.0000238574,0.00001129487,0.00001937855,0.00003579982,0.00001911132],"domain_scores_gemma":[0.999916,0.00001778293,0.00001974428,0.000008030316,0.00002070369,0.00001764027],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001203074,0.00002037779,0.0001496143,0.00005474306,0.000009632472,0.00006085414,0.00002986992,0.0002043977,0.992529,0.0002315794,0.0000495446,0.006540026],"study_design_scores_gemma":[0.000006716568,0.0001116472,0.0001616125,0.000002652529,0.000007174571,0.0000412998,0.000009144137,0.0002986927,0.9982443,0.00002210098,0.001092789,0.000001931061],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.984405,0.004035424,0.006843601,0.0000879637,0.00003788138,0.0000471302,0.0001256363,0.00006579499,0.004351561],"genre_scores_gemma":[0.9866543,0.002766625,0.005389967,0.00002380287,0.00001100494,0.00002209967,0.0001841015,0.00002322355,0.004924765],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009111962,"threshold_uncertainty_score":0.003048301,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03864592001182145,"score_gpt":0.3644090722907562,"score_spread":0.3257631522789348,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}