{"id":"W2952490402","doi":"10.1002/chin.200905113","title":"ChemInform Abstract: Palladium‐Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Intramolecular force; Palladium; Catalysis; Coupling (piping); Combinatorial chemistry; Organic chemistry; Mechanical engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002381043,0.0002520611,0.0003667403,0.0001256373,0.00004144434,0.00001944258,0.000191789,0.0002322532,0.00107122],"category_scores_gemma":[0.0003869307,0.000262386,0.00007967516,0.0003261628,0.000107492,0.0002462946,0.00005490677,0.0002042548,0.000005580268],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001326254,"about_ca_system_score_gemma":0.0001055432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004694109,"about_ca_topic_score_gemma":0.000005253566,"domain_scores_codex":[0.9985057,3.743002e-8,0.0006475066,0.0002625983,0.0002947364,0.0002894832],"domain_scores_gemma":[0.9989464,0.0001540535,0.0002830347,0.000360812,0.0001334729,0.0001222324],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001855478,0.0001376767,0.0007540892,0.0005763131,0.00006256134,0.00001835104,0.0006968394,0.00006818709,0.8268781,0.0004818527,0.000583284,0.1695572],"study_design_scores_gemma":[0.0009789184,0.000009490728,0.004654041,0.0001529318,0.00002426217,0.00003762327,0.0003496027,0.0002919834,0.9906232,0.0003040945,0.002294323,0.0002795686],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.656218,0.0002983572,0.000008013946,0.0001366743,0.00005531678,0.0001239983,0.00002255605,0.0001080756,0.343029],"genre_scores_gemma":[0.996886,0.00007520739,0.0001734094,0.00007461178,0.0000679176,0.00001169382,0.0003853225,0.00002012449,0.002305743],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3407233,"threshold_uncertainty_score":0.9999828,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0141319536844275,"score_gpt":0.2620899893323227,"score_spread":0.2479580356478952,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}