{"id":"W2952492986","doi":"10.1002/chin.200726100","title":"Enantioselective Catalytic Ring Expansion of Methylenecyclopropane Carboxamides Promoted by a Chiral Magnesium Lewis Acid.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Methylenecyclopropane; Enantioselective synthesis; Ring (chemistry); Catalysis; Lewis acids and bases; Magnesium; Combinatorial chemistry; Organic chemistry; Medicinal chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003240705,0.0003636606,0.0004313614,0.0001429018,0.000100104,0.00002498718,0.0003075629,0.0002913216,0.0002951825],"category_scores_gemma":[0.0001984708,0.0003467233,0.0001576196,0.0003972524,0.0001013618,0.000277308,0.0001230554,0.0003612709,0.00002809393],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003262068,"about_ca_system_score_gemma":0.0001261645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001371674,"about_ca_topic_score_gemma":0.0000476233,"domain_scores_codex":[0.9977433,8.276787e-7,0.000713104,0.00042041,0.0005084142,0.0006139652],"domain_scores_gemma":[0.9985667,0.00006587508,0.0004247769,0.0005211676,0.0002367903,0.0001847144],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008382554,0.00005464241,0.00006449202,0.0005521999,0.00003371914,0.000009046766,0.001212075,2.187672e-7,0.8327726,0.00003120435,0.0000641263,0.1651219],"study_design_scores_gemma":[0.0008125551,0.00006151277,0.00009617095,0.00008382209,0.00007774001,0.00006997169,0.001745581,0.00003125214,0.9946285,0.00008464523,0.00192195,0.0003862691],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6558801,0.0004512653,0.0001099027,0.00001600678,0.000118995,0.0002487793,0.00004333508,0.0002623998,0.3428692],"genre_scores_gemma":[0.9898127,0.00002653534,0.0004963574,0.00001424725,0.0001170899,0.00003001887,0.0002377818,0.00006161084,0.009203625],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3339326,"threshold_uncertainty_score":0.9998985,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008269343270842111,"score_gpt":0.2297873599514408,"score_spread":0.2215180166805987,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}