{"id":"W2952510649","doi":"10.1055/s-2001-10808","title":"Conversion of Iodocyclopropanes into Cyclopropylzinc Chlorides and Pd(0)-Catalyzed Cross-Coupling of the Latter Derivatives with Alkenyl Iodides and Iodobenzene: Stereospecific Synthesis of 1,2-Bisalkenylcyclopropanes and 1-Alkenyl-2-phenylcyclopropanes","year":2001,"lang":"en","type":"article","venue":"Synthesis","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Transmetalation; Iodobenzene; Palladium; Stereospecificity; Catalysis; Metalation; Medicinal chemistry; Chloride; Coupling reaction; Zinc; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001467059,0.0005250908,0.0001907872,0.0002578957,0.0001579269,0.000235931,0.0004085186,0.0002924292,0.001574216],"category_scores_gemma":[0.0001807078,0.0002422645,0.000184336,0.0002269992,0.0002268473,0.0002638695,0.0002263416,0.0005188381,0.0005356501],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003091962,"about_ca_system_score_gemma":0.0003661137,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000555772,"about_ca_topic_score_gemma":0.001287498,"domain_scores_codex":[0.999872,0.00001147688,0.00001013467,0.00002670823,0.00004130407,0.00003831809],"domain_scores_gemma":[0.9999207,0.00001187142,0.00002295402,0.000009264555,0.00001196127,0.00002324666],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004447846,0.00001550214,0.000074312,0.00005427079,0.000005988511,0.0001194367,0.0000328901,0.0001574654,0.9972937,0.0002612526,0.00003950054,0.001901243],"study_design_scores_gemma":[0.000006460542,0.00007473252,0.0002474618,0.000001943675,0.00000541007,0.0001033625,0.000008064225,0.00009385696,0.9981272,0.0000241092,0.001303676,0.000003906908],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9803105,0.002286602,0.009156177,0.0001309565,0.0000508949,0.0001154738,0.0003025656,0.0001697702,0.007477021],"genre_scores_gemma":[0.9874144,0.001881201,0.005983695,0.00005142059,0.00001032325,0.00006031972,0.0004613699,0.000040916,0.004096238],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001574216,"threshold_uncertainty_score":0.005266309,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009168685882033284,"score_gpt":0.2210766286453464,"score_spread":0.2119079427633131,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}