{"id":"W2952522340","doi":"10.1021/jo062188w","title":"Single-Isomer Iodochlorination of Alkynes and Chlorination of Alkenes Using Tetrabutylammonium Iodide and Dichloroethane","year":2007,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Alkene; Dichloroethane; Iodine monochloride; Alkyne; Stereoselectivity; Iodide; Iodine; 1,2-Dichloroethane; Organic chemistry; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002341208,0.000481148,0.0002744706,0.0002634914,0.0001741517,0.0002393938,0.0003824957,0.0002478323,0.0008254172],"category_scores_gemma":[0.0002239976,0.0002401901,0.0002764793,0.0002411562,0.0002843935,0.000240894,0.0003444841,0.0003885884,0.0003028746],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004574321,"about_ca_system_score_gemma":0.0003743393,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000722247,"about_ca_topic_score_gemma":0.002487592,"domain_scores_codex":[0.9997686,0.0000229335,0.00001609795,0.00004823851,0.00006181738,0.00008234182],"domain_scores_gemma":[0.9998913,0.00001640368,0.00003470942,0.00001931994,0.00001814021,0.00002021023],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004313283,0.00000598701,0.00007014429,0.00005406098,0.000005261027,0.00006851972,0.00003231683,0.00007059654,0.9980198,0.0001706104,0.0000264521,0.001433023],"study_design_scores_gemma":[0.000005183063,0.00004615849,0.0002143436,0.000001783143,0.00000395275,0.0001292097,0.00001114902,0.00007894282,0.9985974,0.00001550266,0.0008935648,0.000002671449],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9834198,0.001777491,0.009237222,0.00008346372,0.00002529159,0.00006947276,0.0002190848,0.000103749,0.005064388],"genre_scores_gemma":[0.9917135,0.0009659354,0.004595973,0.00003180559,0.000004903036,0.00003207962,0.0002349541,0.00003094803,0.002389988],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008254172,"threshold_uncertainty_score":0.003318965,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01791047740329685,"score_gpt":0.2373473328176087,"score_spread":0.2194368554143118,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}