{"id":"W2952523854","doi":"10.1021/ol005502w","title":"Tandem Oxy-Cope/Transannular Ene Reaction of 1,2-Divinylcyclohexanols","year":2000,"lang":"es","type":"article","venue":"Organic Letters","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Ene reaction; Tandem; Combinatorial chemistry; Stereochemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002817031,0.0004161028,0.0006668125,0.0001527131,0.0001356515,0.00007655708,0.0005179418,0.000356204,0.01142638],"category_scores_gemma":[0.0000771656,0.0004287292,0.0004039377,0.0008998895,0.000148866,0.0002146669,0.00003576057,0.0003433442,0.0004604557],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000239068,"about_ca_system_score_gemma":0.0000795653,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002211468,"about_ca_topic_score_gemma":0.000004787596,"domain_scores_codex":[0.9974384,0.00007890016,0.000715168,0.000621788,0.0006304193,0.0005153029],"domain_scores_gemma":[0.9983664,0.0001750533,0.0003085239,0.0009406866,0.00005623903,0.0001531635],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003967489,0.00018821,0.00244317,0.0001398432,0.0004581573,0.00002538539,0.0002714547,0.00000398613,0.9019351,0.000008965826,0.004678078,0.08980798],"study_design_scores_gemma":[0.000677521,0.00003226817,0.006979902,0.0001862384,0.0006438885,0.00002529619,0.0001810325,0.00001684327,0.949604,0.000006203494,0.04117676,0.0004700831],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.981748,0.001301087,0.0001172547,0.002805415,0.0001306678,0.0001179527,0.00005951591,0.00009123157,0.01362884],"genre_scores_gemma":[0.9958363,0.001532274,0.00008362719,0.0006122029,0.0004708965,0.000009847185,0.00005545271,0.00009912159,0.001300237],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08933789,"threshold_uncertainty_score":0.9998165,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005894745808344092,"score_gpt":0.1961734425742838,"score_spread":0.1902786967659398,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}