{"id":"W2952528823","doi":"10.1002/jhet.5570430134","title":"A series of 1‐[2‐aryl‐1‐diazenyl]‐3‐({3‐[2‐aryl‐1‐diazenyl]perhydrobenzo[<i>d</i>]imidazol‐1‐yl}methyl)perhydrobenzo[<i>d</i>]imidazoles. Synthesis and characterization","year":2006,"lang":"en","type":"article","venue":"Journal of Heterocyclic Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"Dalhousie University","keywords":"Chemistry; Aryl; Methylene; Triazene; Proton NMR; Stereochemistry; NMR spectra database; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Spectral line; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003228077,0.0007412066,0.001308658,0.000179172,0.0002098517,0.0001516433,0.0006318289,0.0006536475,0.001054838],"category_scores_gemma":[0.0003086466,0.000709837,0.0006433389,0.000333151,0.0003103675,0.0008053528,0.0002255575,0.0008267078,0.000007602771],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002923687,"about_ca_system_score_gemma":0.0001316396,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006877798,"about_ca_topic_score_gemma":0.000008713703,"domain_scores_codex":[0.9956357,0.00002263893,0.002047245,0.0006458295,0.0009001979,0.0007483311],"domain_scores_gemma":[0.9961982,0.0003245543,0.001911031,0.0007334744,0.000357472,0.0004753057],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002907728,0.0004586478,0.0007335081,0.0008614248,0.0001870209,0.00008153637,0.0001205081,0.00005275014,0.9944736,0.00007032583,0.0003474645,0.002322375],"study_design_scores_gemma":[0.001263604,0.0000426012,0.0003308067,0.0006305108,0.0003185913,0.001391902,0.0002229288,0.000240603,0.9868646,0.0005605032,0.007481866,0.0006514397],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944481,0.0008113059,0.0001962486,0.0004682759,0.0002134374,0.0001125503,0.000174769,0.000098431,0.003476891],"genre_scores_gemma":[0.9965346,0.0009677527,0.0006631192,0.00007495416,0.0009738285,0.00002908004,0.00009832845,0.0001236054,0.0005347226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007609021,"threshold_uncertainty_score":0.9998583,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00525867696347588,"score_gpt":0.1936377685770033,"score_spread":0.1883790916135275,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}