{"id":"W2952547162","doi":"10.1021/ol0528888","title":"A One-Pot Synthesis and Functionalization of Polyynes","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Transmetalation; Chemistry; Carbenoid; Acetylide; Electrophile; Surface modification; Derivatization; Aryl; Combinatorial chemistry; Palladium; Photochemistry; Catalysis; Organic chemistry; Rhodium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001981562,0.0008873516,0.000362281,0.0002816168,0.0003323206,0.0002819131,0.0006627612,0.0003536098,0.003798929],"category_scores_gemma":[0.0001774134,0.0002480503,0.0003461475,0.0002805558,0.0001876535,0.0004460771,0.0005890701,0.0006759028,0.001590539],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002885908,"about_ca_system_score_gemma":0.0003476645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000377567,"about_ca_topic_score_gemma":0.0007814122,"domain_scores_codex":[0.9997072,0.00003386443,0.00003320158,0.00008186447,0.00006825971,0.00007552873],"domain_scores_gemma":[0.9999102,0.00001350461,0.00001664807,0.00002780434,0.00001293027,0.00001891107],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007028181,0.00009235207,0.00007588536,0.0002597989,0.0000279774,0.0004157026,0.00007043519,0.0005544872,0.9820109,0.001512121,0.0007550013,0.0141552],"study_design_scores_gemma":[0.00002393208,0.0002169739,0.0003937202,0.000008621382,0.00001257819,0.0004138396,0.000009946677,0.0003575399,0.983414,0.0001511578,0.01498406,0.00001368058],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6748171,0.007914112,0.2528979,0.0006836143,0.0008229927,0.002200647,0.003998067,0.00235443,0.05431111],"genre_scores_gemma":[0.9031225,0.006539542,0.06178574,0.0002308131,0.00006082597,0.0006971275,0.001997161,0.0002756003,0.02529077],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003798929,"threshold_uncertainty_score":0.01270866,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007620782317205366,"score_gpt":0.2024580516974843,"score_spread":0.194837269380279,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}