{"id":"W2952547885","doi":"10.1139/v05-043","title":"Pd(0)PhCOOH catalyzed addition of oxygen pronucleophiles to allenes and internal alkynes","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Catalysis; Benzoic acid; Palladium; Organic chemistry; Medicinal chemistry; Oxygen atom; Carboxylic acid; Molecule","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001476657,0.0001508335,0.0003110624,0.000120777,0.00005765335,0.00003924917,0.0003201252,0.0001167422,0.001623201],"category_scores_gemma":[0.000274004,0.0001441021,0.0001351737,0.0001377778,0.000088064,0.0001220616,0.00002362035,0.0001509118,0.000006345531],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001339976,"about_ca_system_score_gemma":0.0003525912,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007159345,"about_ca_topic_score_gemma":0.001031037,"domain_scores_codex":[0.9989406,0.000006237967,0.000468903,0.0001553408,0.0002000157,0.0002288714],"domain_scores_gemma":[0.9985828,0.00004823687,0.0003223865,0.0002006721,0.0001911691,0.0006546898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009975218,0.00008738835,0.004534538,0.0004661594,0.0005727849,0.0001281751,0.001574273,0.00009104335,0.7156717,0.00001609857,0.01849763,0.2582605],"study_design_scores_gemma":[0.0003596024,0.00001237107,0.001189441,0.0002540554,0.00008153456,0.000275386,0.0008402438,0.00001864999,0.9514023,0.00004511213,0.04532172,0.0001996105],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9836711,0.002031266,0.00003972298,0.0008182162,0.00003341023,0.00002170853,0.0001313541,0.000005209764,0.01324796],"genre_scores_gemma":[0.9981115,0.00006362801,0.000418892,0.00005114278,0.0005666658,0.000002812149,0.00001806779,0.00001913788,0.00074817],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2580609,"threshold_uncertainty_score":0.9992895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006638480517209567,"score_gpt":0.1930884439934537,"score_spread":0.1864499634762442,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}