{"id":"W2952588228","doi":"10.1080/00397910008086966","title":"Effect of aryl Substituents on Rate of Desulfonylation of Aryl Alkyl Sulfones: Superiority of<i>p</i>-Fluorophenyl- and 2-Naphthyl Sulfones","year":2000,"lang":"en","type":"article","venue":"Synthetic Communications","topic":"Organic and Inorganic Chemical Reactions","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Universidad de Oviedo","keywords":"Chemistry; Aryl; Alkyl; Toluene; Medicinal chemistry; Sulfone; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003672305,0.0002138627,0.0005710469,0.00007905901,0.0001066738,0.000006043786,0.0005998297,0.0001629172,0.0009521018],"category_scores_gemma":[0.000505536,0.0002007818,0.0001607444,0.0003210991,0.0007595774,0.00009873863,0.0001495768,0.0002520226,0.00001200526],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004246021,"about_ca_system_score_gemma":0.00007646253,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003566565,"about_ca_topic_score_gemma":0.00002433477,"domain_scores_codex":[0.9985306,0.00006007238,0.0007896124,0.0002337511,0.0002097936,0.0001761572],"domain_scores_gemma":[0.9959111,0.00169128,0.0003548804,0.001815155,0.0001462741,0.00008136505],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001561868,0.000446754,0.00516233,0.00034157,0.00008573213,2.218442e-7,0.0003893136,0.000007983866,0.9833677,0.0007561201,0.00001278548,0.009273278],"study_design_scores_gemma":[0.0007121972,0.0001335717,0.003995015,0.0003631914,0.0001895929,0.000007579804,0.0001318299,0.0001625138,0.9933459,0.0003803746,0.0004275597,0.0001506748],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9932763,0.0008572862,0.00002025202,0.0001759514,0.00002792713,0.0001721058,0.0001762848,0.00003015793,0.00526374],"genre_scores_gemma":[0.9974447,0.00208668,0.000209928,0.000005320004,0.00001271599,0.00001666937,0.00006544468,0.00002646856,0.0001320827],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009978174,"threshold_uncertainty_score":0.9999611,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008416434343072756,"score_gpt":0.248401837076162,"score_spread":0.2399854027330892,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}