{"id":"W2952588228","doi":"10.1080/00397910008086966","title":"Effect of aryl Substituents on Rate of Desulfonylation of Aryl Alkyl Sulfones: Superiority of<i>p</i>-Fluorophenyl- and 2-Naphthyl Sulfones","year":2000,"lang":"en","type":"article","venue":"Synthetic Communications","topic":"Organic and Inorganic Chemical Reactions","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Universidad de Oviedo","keywords":"Chemistry; Aryl; Alkyl; Toluene; Medicinal chemistry; Sulfone; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004795662,0.0005362186,0.0002363451,0.0001522135,0.0001384081,0.000278281,0.0002276004,0.0002261619,0.002377389],"category_scores_gemma":[0.001042103,0.0001980605,0.0001335949,0.0001906829,0.0001959929,0.0003844246,0.0001676927,0.000334846,0.0004922631],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002280218,"about_ca_system_score_gemma":0.0003583239,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001682813,"about_ca_topic_score_gemma":0.001682852,"domain_scores_codex":[0.9997965,0.0000519325,0.00002413586,0.00004185416,0.00003294665,0.00005272471],"domain_scores_gemma":[0.9990609,0.0004214527,0.000171578,0.00006604534,0.0001387873,0.0001412468],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001558376,0.00003210035,0.0003531738,0.00005342388,0.00001086117,0.000068212,0.00007036822,0.0002208958,0.9939994,0.00009987503,0.00006734348,0.003465865],"study_design_scores_gemma":[0.0000158728,0.0004251947,0.0007249006,0.000002582318,0.000009865192,0.00002998432,0.00001529931,0.000318746,0.997946,0.000007505322,0.0004986021,0.000005570417],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973165,0.0005068934,0.0005895066,0.00004380062,0.00002100693,0.00001205001,0.0001813817,0.00005168121,0.001277071],"genre_scores_gemma":[0.9973321,0.0006573063,0.0006199337,0.00001273279,0.00001116236,0.00001217796,0.0002131567,0.00003808061,0.001103383],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002377389,"threshold_uncertainty_score":0.007953167,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008416434343072756,"score_gpt":0.248401837076162,"score_spread":0.2399854027330892,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}