{"id":"W2952600979","doi":"10.1021/ol051947e","title":"Intermolecular Heck-Type Coupling of Aryl Iodides and Allylic Acetates","year":2005,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Allylic rearrangement; Palladium; Aryl; Heck reaction; Intermolecular force; Catalysis; Ligand (biochemistry); Base (topology); Chloride; Coupling (piping); Organic chemistry; Medicinal chemistry; Molecule; Alkyl; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007267061,0.0001443674,0.0001832433,0.00004647856,0.00006555304,0.00004811025,0.0001553087,0.00006485273,0.0004919202],"category_scores_gemma":[0.0001126144,0.0001510504,0.00005228836,0.0001120748,0.0001538758,0.00009489482,0.00008487279,0.0001745673,0.00005607062],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009551111,"about_ca_system_score_gemma":0.00003397449,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002628266,"about_ca_topic_score_gemma":0.00001278932,"domain_scores_codex":[0.9991769,1.539637e-7,0.0002350859,0.0002459117,0.0001373767,0.0002045959],"domain_scores_gemma":[0.9993838,0.00008346374,0.0001022628,0.0003280423,0.00003933647,0.00006309813],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001088656,0.00002720199,0.001812399,0.00005452202,0.00005963921,0.000008684853,0.0002765196,0.00010683,0.9969656,0.00001254285,0.0003983864,0.000266759],"study_design_scores_gemma":[0.0003347604,0.000006666343,0.0004645578,0.00005285874,0.00005155983,0.00006212209,0.00008692877,0.001176666,0.9968978,0.000009889898,0.0007026758,0.0001535435],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976087,0.0002682603,0.0000795308,0.001825914,0.00006525952,0.00003524868,0.000005748007,0.0000795692,0.0000317372],"genre_scores_gemma":[0.9991794,0.00004284818,0.0001061324,0.0004200996,0.0001173456,0.000001980332,0.0000208587,0.00003713479,0.00007417848],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001570689,"threshold_uncertainty_score":0.6159657,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007796371201296912,"score_gpt":0.2311883343565785,"score_spread":0.2233919631552815,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}