{"id":"W2952600979","doi":"10.1021/ol051947e","title":"Intermolecular Heck-Type Coupling of Aryl Iodides and Allylic Acetates","year":2005,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Allylic rearrangement; Palladium; Aryl; Heck reaction; Intermolecular force; Catalysis; Ligand (biochemistry); Base (topology); Chloride; Coupling (piping); Organic chemistry; Medicinal chemistry; Molecule; Alkyl; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004911134,0.000659929,0.0003927804,0.0004346622,0.0005101789,0.0003973057,0.0008204698,0.0003205903,0.008226273],"category_scores_gemma":[0.0004041076,0.0002746062,0.0003047583,0.0005017013,0.0002970675,0.0005798051,0.0005713421,0.0007245957,0.002795304],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003747172,"about_ca_system_score_gemma":0.0004625855,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006029595,"about_ca_topic_score_gemma":0.00204602,"domain_scores_codex":[0.9996884,0.0000424859,0.0000183563,0.00005803623,0.00005682579,0.0001359012],"domain_scores_gemma":[0.999884,0.0000343024,0.00001306382,0.00002082271,0.00001725873,0.00003046456],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000693387,0.0002858527,0.0007498213,0.001104442,0.0001427533,0.001643571,0.0003296066,0.001990454,0.9350729,0.01094778,0.003488116,0.04355128],"study_design_scores_gemma":[0.00003776666,0.0002879298,0.0004611413,0.00001396286,0.00004372315,0.0003299064,0.00002746742,0.0003911408,0.9871912,0.0003427109,0.01085577,0.00001721574],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7658579,0.01452545,0.07821869,0.0006489324,0.0008817706,0.0005755594,0.001642233,0.001559181,0.1360902],"genre_scores_gemma":[0.9294963,0.008969265,0.01733459,0.0001470763,0.0002003756,0.0001357602,0.0008436418,0.00008254576,0.04279042],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008226273,"threshold_uncertainty_score":0.02751964,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007796371201296912,"score_gpt":0.2311883343565785,"score_spread":0.2233919631552815,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}