{"id":"W2952605593","doi":"10.1021/ic302221y","title":"Synthesis and Lewis Acid Properties of (ReO<sub>3</sub>F)<sub>∞</sub> and the X-ray Crystal Structures of (HF)<sub>2</sub>ReO<sub>3</sub>F·HF and [N(CH<sub>3</sub>)<sub>4</sub>]<sub>2</sub>-[{ReO<sub>3</sub>(μ-F)}<sub>3</sub>(μ<sub>3</sub>-O)]·CH<sub>3</sub>CN","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Raman spectroscopy; Rhenium; Lewis acids and bases; Crystallography; Molecule; Crystal structure; Anhydrous; Hydrogen fluoride; Nuclear magnetic resonance spectroscopy; Stoichiometry; X-ray crystallography; Infrared spectroscopy; Physical chemistry; Inorganic chemistry; Stereochemistry; Diffraction; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001731577,0.0003295433,0.0001964464,0.0002358647,0.0001763342,0.0001803514,0.000290444,0.0002988843,0.001271115],"category_scores_gemma":[0.0002945676,0.0001560372,0.000193874,0.0002201712,0.0001545889,0.0002104301,0.0001540333,0.0003585228,0.0003704824],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002698288,"about_ca_system_score_gemma":0.0002456216,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001662976,"about_ca_topic_score_gemma":0.002880245,"domain_scores_codex":[0.9998955,0.000006281504,0.00001045792,0.00002283492,0.00004542142,0.00001947375],"domain_scores_gemma":[0.9998987,0.00001336903,0.00002807093,0.00001142719,0.00003335375,0.00001511053],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006790661,0.000009915632,0.0001630919,0.00006932392,0.000004659306,0.00005009651,0.00001860252,0.0002244138,0.9964289,0.0002244686,0.00008713696,0.002651563],"study_design_scores_gemma":[0.00001144182,0.0001144885,0.001729683,0.000007688211,0.000007358326,0.0001678066,0.00002239616,0.0006043646,0.993939,0.00004253901,0.003340296,0.00001291271],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899381,0.001203374,0.005040589,0.00005307353,0.00002306209,0.00005998462,0.001013478,0.00008262869,0.00258581],"genre_scores_gemma":[0.9785451,0.001427585,0.01312573,0.0000476841,0.00001633037,0.0001043957,0.0025908,0.00007172069,0.004070634],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001662976,"threshold_uncertainty_score":0.004252374,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006218979201372568,"score_gpt":0.1757941269878563,"score_spread":0.1695751477864837,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}