{"id":"W2952621196","doi":"10.1002/chin.201022090","title":"ChemInform Abstract: Desymmetrization of 4‐Hydroxy‐2,5‐cyclohexadienones by Radical Cyclization: Synthesis of Optically Pure γ‐Lactones.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Desymmetrization; Chemistry; Optically active; Radical cyclization; Combinatorial chemistry; Stereochemistry; Organic chemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002705723,0.0009015194,0.0002895686,0.0004431141,0.0002631512,0.0003271174,0.0005549029,0.0003142417,0.01328061],"category_scores_gemma":[0.0002186488,0.0002269447,0.000324973,0.0004229227,0.0003276027,0.0007343226,0.0005055917,0.0009720478,0.003205267],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004673503,"about_ca_system_score_gemma":0.0007285859,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006487423,"about_ca_topic_score_gemma":0.001369342,"domain_scores_codex":[0.9998527,0.00001670908,0.00000836629,0.00003158778,0.00002696548,0.00006373761],"domain_scores_gemma":[0.9999279,0.00001034427,0.00001659485,0.00001231056,0.000008715333,0.0000241791],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001003654,0.0003018064,0.0002894351,0.001310688,0.00009507035,0.0009211302,0.0005728274,0.001712368,0.8829511,0.009245392,0.01493781,0.08665874],"study_design_scores_gemma":[0.0001822733,0.0008848664,0.0009519294,0.000061832,0.00003810242,0.000460784,0.00008099622,0.0005660207,0.9490294,0.0009900685,0.04670613,0.00004762562],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7322869,0.02241977,0.06834882,0.002385925,0.002968336,0.000984365,0.006179035,0.002431905,0.161995],"genre_scores_gemma":[0.9339735,0.01241163,0.009415329,0.000378381,0.0002082866,0.0001589122,0.002064966,0.0002315187,0.04115747],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01328061,"threshold_uncertainty_score":0.04442805,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006547295803806848,"score_gpt":0.2281728518569504,"score_spread":0.2216255560531435,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}