{"id":"W2952647784","doi":"10.1021/jo050727b","title":"Total Synthesis of<i>N</i>-Malayamycin A and Related Bicyclic Purine and Pyrimidine Nucleosides","year":2005,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Bicyclic molecule; Chemistry; Sulfonium; Pyrimidine; Purine; Stereochemistry; Ring (chemistry); Metathesis; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000141119,0.0004545338,0.0004491698,0.0003607039,0.0004022654,0.0003070506,0.0004219044,0.0002245889,0.003011541],"category_scores_gemma":[0.0001669355,0.0002103042,0.0003304043,0.0003872217,0.0001730349,0.0003326671,0.0004665231,0.0005176286,0.001399385],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003661744,"about_ca_system_score_gemma":0.0005523149,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007244031,"about_ca_topic_score_gemma":0.001728984,"domain_scores_codex":[0.9998521,0.00001982458,0.00001710519,0.00002692621,0.0000504693,0.00003357251],"domain_scores_gemma":[0.9999079,0.00001064816,0.00001632298,0.00001651711,0.00001706775,0.0000316048],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009265928,0.00002193226,0.00006417133,0.0002171441,0.00001393613,0.0001463625,0.00006061319,0.0004327959,0.9845253,0.001286634,0.0002128786,0.01292572],"study_design_scores_gemma":[0.0000306469,0.0005636598,0.0006374093,0.00002345959,0.0000399077,0.0008491891,0.00003161032,0.0004920386,0.9719967,0.0005284837,0.02477685,0.00003007597],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8439485,0.01276304,0.07233784,0.0002292445,0.0003585647,0.0007240298,0.004952101,0.0008969859,0.06378962],"genre_scores_gemma":[0.8976384,0.007919428,0.06875091,0.0001177906,0.00003106616,0.0004678183,0.00232812,0.0001465366,0.02259986],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003011541,"threshold_uncertainty_score":0.01007468,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004856420673904636,"score_gpt":0.1879352813638455,"score_spread":0.1830788606899409,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}