{"id":"W2952656232","doi":"10.1016/j.tetlet.2003.10.129","title":"Bismuth triflate-catalyzed mild and efficient epoxide opening by aromatic amines under aqueous conditions","year":2003,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":162,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Epoxide; Trifluoromethanesulfonate; Aqueous solution; Bismuth; Catalysis; Organic chemistry; Ring (chemistry); Aqueous medium; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003044196,0.0005304294,0.0002648018,0.0002280637,0.0002343024,0.0002212758,0.0004113372,0.0004595775,0.001260217],"category_scores_gemma":[0.0002218661,0.0002675978,0.0002328049,0.0001137158,0.0002447391,0.0005932277,0.0003796094,0.0005311939,0.0006324861],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002275008,"about_ca_system_score_gemma":0.0002213727,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004294958,"about_ca_topic_score_gemma":0.0008642634,"domain_scores_codex":[0.9998347,0.00002203671,0.00001606664,0.000026481,0.00004000961,0.00006060845],"domain_scores_gemma":[0.9999304,0.00001677763,0.00001927415,0.00001181655,0.00001106564,0.00001067473],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001471625,0.00003790787,0.00006620202,0.0001098182,0.000009334695,0.0001859653,0.00007530702,0.0001629949,0.9926206,0.000771359,0.0002844701,0.005528808],"study_design_scores_gemma":[0.00001811677,0.0001100837,0.0002741201,0.00000414992,0.000006555568,0.0001595745,0.000008014528,0.0003973166,0.9968296,0.00008519376,0.002099909,0.000007459334],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9680434,0.002078416,0.01463278,0.0002718113,0.0001226491,0.0000928548,0.0002138472,0.000380419,0.01416384],"genre_scores_gemma":[0.9916608,0.0009591245,0.003508519,0.00003953984,0.00002713967,0.00003011037,0.0001712119,0.0000423301,0.003561239],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001260217,"threshold_uncertainty_score":0.004215837,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0109077931343602,"score_gpt":0.2255109682749872,"score_spread":0.214603175140627,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}