{"id":"W2952683237","doi":"10.1002/ejoc.201101222","title":"Regioselective Photochemical Rearrangement of <i>N</i>‐Mesyloxylactams","year":2012,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Sherbrooke","keywords":"Chemistry; Regioselectivity; Ring strain; Oxygen atom; Ring (chemistry); Photochemistry; Stereochemistry; Oxygen; Cope rearrangement; Organic chemistry; Catalysis; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006864968,0.0003151709,0.0004686532,0.00003336841,0.0000629451,0.00001969658,0.0006221367,0.00009638436,0.01442308],"category_scores_gemma":[0.0006200167,0.0003033966,0.0002862074,0.0002837305,0.0001835617,0.0001515352,0.000166278,0.0007754299,0.00005160621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003008038,"about_ca_system_score_gemma":0.0001527601,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":6.855329e-7,"about_ca_topic_score_gemma":7.171199e-8,"domain_scores_codex":[0.9977595,0.00005812322,0.0009642249,0.0002264909,0.0005410617,0.0004506181],"domain_scores_gemma":[0.9973454,0.0001256769,0.001206887,0.000531208,0.0003809086,0.0004099246],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008959159,0.000416113,0.001749217,0.0001973403,0.0002471768,0.000038447,0.0004728552,4.836155e-7,0.9932132,0.000002120214,0.00285913,0.0007143659],"study_design_scores_gemma":[0.001103285,0.0000265733,0.0004219935,0.000171417,0.0001498294,0.001054317,0.000764477,0.000001332845,0.9790105,0.000008787005,0.0170225,0.0002650197],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8739843,0.0006297076,0.0001330202,0.0001170487,0.0001192908,0.00003577237,0.00001971568,0.00003992108,0.1249213],"genre_scores_gemma":[0.9957798,0.00006882195,0.0005969908,0.00002707689,0.001291518,9.735912e-7,0.000009825325,0.0000971848,0.002127824],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1227934,"threshold_uncertainty_score":0.9999418,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01293504271258186,"score_gpt":0.2207572915471435,"score_spread":0.2078222488345617,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}