{"id":"W2952690960","doi":"10.1002/chin.201604130","title":"ChemInform Abstract: Stereoselective and Regiodivergent Allylic Suzuki—Miyaura Cross‐Coupling of 2‐Ethoxydihydropyranyl Boronates: Synthesis and Confirmation of Absolute Stereochemistry of Diospongin B.","year":2016,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Allylic rearrangement; Stereoselectivity; Stereochemistry; Coupling (piping); Coupling reaction; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001926936,0.0004870962,0.00009123732,0.0003229066,0.0002479784,0.0002097611,0.0003043932,0.0002205214,0.007186817],"category_scores_gemma":[0.0001396245,0.0001954863,0.00009624034,0.0002279051,0.0002073913,0.0002452313,0.0002532976,0.0004594211,0.002113387],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003503591,"about_ca_system_score_gemma":0.0005649337,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001077762,"about_ca_topic_score_gemma":0.002749869,"domain_scores_codex":[0.9998935,0.00001629326,0.000006057766,0.00002717882,0.00002725102,0.0000295886],"domain_scores_gemma":[0.9999299,0.00001005782,0.00001607312,0.00001315136,0.00001046791,0.00002035235],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001871205,0.00002736536,0.0001512572,0.00008442415,0.000005693662,0.0001537909,0.00004466674,0.0001733035,0.9881752,0.001146338,0.0005181766,0.009332755],"study_design_scores_gemma":[0.00002370946,0.000120672,0.000643642,0.000006309353,0.00000680646,0.0001867934,0.00001018021,0.0001894451,0.9915075,0.00009685982,0.007203168,0.000004753996],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8614504,0.002596852,0.04259839,0.0004515213,0.000169153,0.000223996,0.003180243,0.0008459036,0.08848359],"genre_scores_gemma":[0.9673812,0.001349682,0.01171118,0.00009752751,0.00001573528,0.00004794385,0.001606367,0.00008859561,0.01770187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007186817,"threshold_uncertainty_score":0.02404237,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01764421709566475,"score_gpt":0.2629266613273477,"score_spread":0.2452824442316829,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}