{"id":"W2952764731","doi":"10.1016/s0957-4166(00)00103-8","title":"P–C bond formation: synthesis of phosphino amino acids by palladium-catalysed cross-coupling","year":2000,"lang":"en","type":"article","venue":"Tetrahedron Asymmetry","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Palladium; Chemistry; Coupling (piping); Amino acid; Polymer chemistry; Organic chemistry; Catalysis; Materials science; Biochemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002426664,0.0003379494,0.0004313712,0.00008098931,0.0001743234,0.00009905062,0.0005312662,0.0003173708,0.01977734],"category_scores_gemma":[0.0002139129,0.000363935,0.0002377953,0.0005153106,0.0001780316,0.000441417,0.00005555938,0.0003111348,0.0002090991],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001479984,"about_ca_system_score_gemma":0.0000492807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002334044,"about_ca_topic_score_gemma":0.000001766594,"domain_scores_codex":[0.9978922,0.000006273018,0.0007446212,0.0004316845,0.0004986457,0.0004265621],"domain_scores_gemma":[0.9985078,0.0002663131,0.0002663249,0.0006665356,0.0001125781,0.0001804753],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002000772,0.000687858,0.02146983,0.001396421,0.0002773521,0.00001745582,0.00029883,0.0001473107,0.8839915,0.0002103649,0.005989515,0.08531348],"study_design_scores_gemma":[0.0006245052,0.00001293849,0.001008478,0.00006560157,0.00007239034,0.00001780377,0.0001359859,0.0009587944,0.9802235,0.00006986118,0.01642092,0.0003892675],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8824965,0.0007299221,0.0001083696,0.0000925896,0.00005602874,0.00005967073,0.000205608,0.0001814929,0.1160698],"genre_scores_gemma":[0.9895262,0.0001476399,0.0003599028,0.00005463483,0.0001384858,0.00002102817,0.0002323071,0.00004965027,0.009470123],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1070298,"threshold_uncertainty_score":0.9998813,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00888867850649051,"score_gpt":0.2439804739414204,"score_spread":0.2350917954349299,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}