{"id":"W2952786258","doi":"10.1002/chin.200737198","title":"A Highly Stereoselective Synthesis of (‐)‐(ent)‐Julifloridine (I) from the Cyclization of an Alanine‐Derived Chloroamine with an Acetylenic Sulfone.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Stereoselectivity; Sulfone; Combinatorial chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001833453,0.0006086836,0.0002846419,0.000255567,0.0002832302,0.0002104187,0.000709945,0.0003170185,0.002616154],"category_scores_gemma":[0.0001800644,0.0001868321,0.0002285733,0.0002608882,0.0002222552,0.0002987632,0.0003840723,0.0005347966,0.001548291],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003932409,"about_ca_system_score_gemma":0.0007493776,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001430766,"about_ca_topic_score_gemma":0.002258006,"domain_scores_codex":[0.9998655,0.00001643641,0.00001000312,0.0000335738,0.00001958443,0.00005490736],"domain_scores_gemma":[0.9999347,0.000006707915,0.00001190746,0.000008916579,0.000009544157,0.00002828294],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000165105,0.00005183787,0.0000726456,0.0002264783,0.00001446598,0.0003761599,0.00007341247,0.0002236748,0.9852423,0.001145969,0.00119288,0.01121513],"study_design_scores_gemma":[0.00005097241,0.000720221,0.000674881,0.00001538178,0.00002080759,0.0005728504,0.00002894135,0.0003295849,0.9821875,0.00018823,0.0151844,0.00002630858],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8108504,0.008157634,0.08001412,0.0008315666,0.0009282106,0.0007918279,0.005620387,0.001784345,0.09102155],"genre_scores_gemma":[0.9674828,0.004077564,0.01727211,0.0001228755,0.0000662506,0.0001359815,0.001681909,0.0001631546,0.008997364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002616154,"threshold_uncertainty_score":0.008751929,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01006321332932204,"score_gpt":0.2210762932970229,"score_spread":0.2110130799677009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}