{"id":"W2952794723","doi":"10.1002/chin.200638059","title":"Single‐Isomer Tetrasubstituted Olefins from Regioselective and Stereospecific Palladium‐Catalyzed Coupling of β‐Chloro‐α‐iodo‐α,β‐unsaturated Esters.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Regioselectivity; Stereospecificity; Catalysis; Palladium; Combinatorial chemistry; Coupling (piping); Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003936542,0.0008250935,0.0002709636,0.0006469687,0.0003173481,0.0003615204,0.0008542858,0.000407604,0.004732745],"category_scores_gemma":[0.0001939191,0.0004381452,0.0003531793,0.0006326203,0.0003094822,0.0006406686,0.0005056893,0.0009864442,0.002363736],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005604874,"about_ca_system_score_gemma":0.0006451913,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009411833,"about_ca_topic_score_gemma":0.002804024,"domain_scores_codex":[0.9997581,0.00002098032,0.00002217479,0.00004855917,0.00004015359,0.0001101134],"domain_scores_gemma":[0.9999245,0.000006953869,0.00001741282,0.00001333307,0.00001374562,0.00002405694],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004869796,0.0001483242,0.0001734369,0.0003629092,0.00004741529,0.0005678111,0.0001574826,0.0006550194,0.9695385,0.003095557,0.00312024,0.02164642],"study_design_scores_gemma":[0.00005181629,0.0002545775,0.0003835114,0.00001814508,0.00002691441,0.0003819184,0.00003667988,0.0003910926,0.9850652,0.0003470572,0.01302096,0.00002221389],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.82744,0.007549705,0.06462963,0.0009635081,0.0007716467,0.0005164513,0.005500755,0.001945116,0.09068313],"genre_scores_gemma":[0.9532784,0.006794883,0.01328286,0.0002006529,0.00005381221,0.0001509657,0.003462153,0.0003133421,0.02246276],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004732745,"threshold_uncertainty_score":0.01583266,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02120666851401611,"score_gpt":0.2355434006872975,"score_spread":0.2143367321732814,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}