{"id":"W2952795619","doi":"10.1002/chin.200541025","title":"Synthetic Applications of (Me<sub>3</sub>SiNSN)<sub>2</sub>E (E: S, Se) in Chalcogen‐Nitrogen Chemistry: Formation and Structural Characterization of Cl<sub>2</sub>TeESN<sub>2</sub> (E: S, Se) and [PPh<sub>4</sub>]<sub>2</sub> [Pd<sub>2</sub>(μ‐Se<sub>2</sub>N<sub>2</sub>S)X<sub>4</sub>] (X: Cl, Br).","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chalcogen; Chemistry; Characterization (materials science); Nitrogen; Nanotechnology; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001879662,0.000259594,0.0001284843,0.0001117799,0.0001815484,0.0002309251,0.0001973219,0.0002499676,0.001374276],"category_scores_gemma":[0.000176619,0.0001299639,0.0001089734,0.0001020438,0.0002545905,0.0001947634,0.0002248705,0.0001262619,0.0002875139],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002406348,"about_ca_system_score_gemma":0.0002119189,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004409773,"about_ca_topic_score_gemma":0.001348073,"domain_scores_codex":[0.9999313,0.00001716731,0.000004672692,0.00001760985,0.00001924513,0.00001001695],"domain_scores_gemma":[0.9999527,0.0000104182,0.00001225196,0.000007105505,0.00001013114,0.000007338977],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001304404,0.00001353814,0.0001470264,0.00007845867,0.000005642322,0.00006857961,0.00002737426,0.0003553875,0.9958769,0.0002967295,0.00005677431,0.002943087],"study_design_scores_gemma":[0.00001942879,0.0001127095,0.0004333843,0.000002841206,0.000004533956,0.0001538666,0.000027867,0.0004532292,0.9967347,0.00009536665,0.001959664,0.000002307443],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9791715,0.002198901,0.007497607,0.0001339375,0.00005074199,0.00008864536,0.0001711456,0.0001076307,0.01057983],"genre_scores_gemma":[0.9919103,0.0006300865,0.004351077,0.00004265949,0.000003788459,0.00002065898,0.0001286394,0.00001656313,0.002896238],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001374276,"threshold_uncertainty_score":0.004597425,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008381756769484409,"score_gpt":0.2073008489867477,"score_spread":0.1989190922172633,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}