{"id":"W2952808439","doi":"10.1021/om000685b","title":"Sequential Insertion of Carbon Monoxide and Imines into Nickel−Methyl Bonds:  A New Route to Imine Hydroacylation","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Imine; Hydroacylation; Carbon monoxide; Nickel; Migratory insertion; Combinatorial chemistry; Organic chemistry; Aldehyde; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001174832,0.0001849248,0.0002819408,0.000242232,0.00004842307,0.00003185424,0.0001520026,0.0001303866,0.001633466],"category_scores_gemma":[0.0001013355,0.0001897375,0.00007317055,0.0009480804,0.00003435059,0.0001445133,0.0000561687,0.00009009169,0.00003548675],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009582151,"about_ca_system_score_gemma":0.00006854923,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009744623,"about_ca_topic_score_gemma":0.0001157104,"domain_scores_codex":[0.9987809,0.00001615702,0.0004167966,0.0003199999,0.0002846303,0.0001815085],"domain_scores_gemma":[0.9992583,0.00003211277,0.0001276486,0.0003189507,0.00006425934,0.0001987616],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008211418,0.000112699,0.002569805,0.00007708674,0.0001706561,0.000003397727,0.001299325,0.0004980747,0.8272423,0.000117944,0.00008921769,0.1677374],"study_design_scores_gemma":[0.001116325,0.00007484951,0.001954187,0.00002939913,0.0003077243,0.00001283718,0.0002069768,0.006373861,0.9691505,0.0004552436,0.01983696,0.0004810946],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991772,0.0003641483,0.000310105,0.000375621,0.00002256579,0.00007668117,0.000009873326,0.00005872311,0.007010303],"genre_scores_gemma":[0.9893528,0.0001590894,0.001185524,0.00008694247,0.0001177853,0.000007944703,0.0001423179,0.0000315348,0.008916011],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1672563,"threshold_uncertainty_score":0.9992792,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01106674075276697,"score_gpt":0.2328691162201784,"score_spread":0.2218023754674114,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}