{"id":"W2952808439","doi":"10.1021/om000685b","title":"Sequential Insertion of Carbon Monoxide and Imines into Nickel−Methyl Bonds:  A New Route to Imine Hydroacylation","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Imine; Hydroacylation; Carbon monoxide; Nickel; Migratory insertion; Combinatorial chemistry; Organic chemistry; Aldehyde; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001994486,0.0005166799,0.0004079535,0.0002144291,0.0002709675,0.0004109208,0.0006055812,0.0003331059,0.001494408],"category_scores_gemma":[0.0002061184,0.000358299,0.0002535167,0.0001405099,0.0003915249,0.0007147609,0.000645596,0.000759185,0.0008682217],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002973648,"about_ca_system_score_gemma":0.0002630095,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002943941,"about_ca_topic_score_gemma":0.0007392696,"domain_scores_codex":[0.9998357,0.00001912136,0.00001724048,0.00004177924,0.00004644964,0.00003958178],"domain_scores_gemma":[0.9998877,0.00001249641,0.0000358486,0.00002349467,0.00001490279,0.0000254742],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001186537,0.00002951562,0.00007466073,0.0001180321,0.00001169253,0.0002359121,0.0001291575,0.0001355746,0.9925432,0.000929354,0.0001084357,0.005565764],"study_design_scores_gemma":[0.0000291217,0.0001533851,0.0001493934,0.000004508567,0.000009377341,0.0002645068,0.0000152921,0.0002735948,0.993681,0.00007287479,0.005335809,0.00001118184],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9386269,0.002659148,0.0399627,0.0003684183,0.0001745676,0.0002197384,0.0003494842,0.0006568889,0.01698222],"genre_scores_gemma":[0.9667976,0.001887181,0.02213141,0.00008787047,0.0000417864,0.0001129331,0.0002277802,0.0001183034,0.008595074],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001494408,"threshold_uncertainty_score":0.00499928,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01106674075276697,"score_gpt":0.2328691162201784,"score_spread":0.2218023754674114,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}