{"id":"W2952808735","doi":"10.1021/ic051451t","title":"Syntheses of [F<sub>5</sub>TeNH<sub>3</sub>][AsF<sub>6</sub>], [F<sub>5</sub>TeN(H)Xe][AsF<sub>6</sub>], and F<sub>5</sub>TeNF<sub>2</sub> and Characterization by Multi-NMR and Raman Spectroscopy and by Electronic Structure Calculations:  The X-ray Crystal Structures of α- and β-F<sub>5</sub>TeNH<sub>2</sub>, [F<sub>5</sub>TeNH<sub>3</sub>][AsF<sub>6</sub>], and [F<sub>5</sub>TeN(H)Xe][AsF<sub>6</sub>]","year":2006,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Sublimation (psychology); Crystallography; Crystal structure; Raman spectroscopy; Crystallization; Solvent; Analytical Chemistry (journal); Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001326036,0.00033636,0.0002805504,0.0002329621,0.0002222023,0.0001649872,0.0004800437,0.0003178895,0.003119061],"category_scores_gemma":[0.0002250534,0.0001695171,0.0001985697,0.0003682362,0.0001191244,0.0002523221,0.0002271373,0.0002622816,0.0009460115],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000290416,"about_ca_system_score_gemma":0.0005452498,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001612104,"about_ca_topic_score_gemma":0.004596398,"domain_scores_codex":[0.9999145,0.000003913475,0.000008535393,0.0000189057,0.00004018945,0.00001384889],"domain_scores_gemma":[0.9999038,0.000005168767,0.00002733198,0.00001487939,0.00003098035,0.00001788418],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001194118,0.00003917136,0.000220205,0.0003523286,0.00001894926,0.0001095495,0.00007255144,0.0008409424,0.9891673,0.0007677542,0.0004496578,0.00784209],"study_design_scores_gemma":[0.00003940398,0.0004303005,0.001943909,0.00001519501,0.00002571405,0.0003209786,0.00004470373,0.001236998,0.977038,0.0001275116,0.01875256,0.00002469726],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9656732,0.00147688,0.01483547,0.0001000152,0.00009830124,0.0003373004,0.001855727,0.0004550478,0.01516809],"genre_scores_gemma":[0.9350173,0.002201012,0.03826931,0.0001119752,0.00003444647,0.0003797222,0.003497813,0.0002053942,0.02028295],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003119061,"threshold_uncertainty_score":0.01043427,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003596955116748799,"score_gpt":0.1880868460789278,"score_spread":0.184489890962179,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}