{"id":"W2952837438","doi":"10.1002/chin.201434093","title":"ChemInform Abstract: Iron(II) Complexes Containing Unsymmetrical P—N—P′ Pincer Ligands for the Catalytic Asymmetric Hydrogenation of Ketones and Imines.","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Pincer movement; Catalysis; Medicinal chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001173734,0.0004132481,0.0001420693,0.0002638831,0.0002278151,0.0003903686,0.0005188477,0.0003591842,0.01279494],"category_scores_gemma":[0.000142705,0.0001465288,0.00007281738,0.0002070688,0.0001684409,0.0003634201,0.0003978646,0.0003896746,0.002329426],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003947589,"about_ca_system_score_gemma":0.0003181245,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004971834,"about_ca_topic_score_gemma":0.0007285571,"domain_scores_codex":[0.9999124,0.00001261146,0.000004099327,0.00001905703,0.00003275671,0.00001906128],"domain_scores_gemma":[0.9999783,0.000003373739,0.000005244714,0.000003038918,0.000004710963,0.000005257144],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001470875,0.0001817133,0.0006352347,0.001309049,0.00005047748,0.0005875009,0.0001319087,0.002290971,0.8196806,0.01681807,0.03276105,0.1240825],"study_design_scores_gemma":[0.0001901093,0.0001933393,0.0007278165,0.00003522707,0.00003320193,0.0004405504,0.00003498872,0.003391805,0.9215384,0.0006537252,0.072742,0.00001880668],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6321012,0.006549272,0.07668432,0.002178227,0.0006292493,0.0004028916,0.004794717,0.005096798,0.2715633],"genre_scores_gemma":[0.9572364,0.002011407,0.01207932,0.0003024205,0.00005712981,0.00009828519,0.002345793,0.0001635596,0.0257057],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01279494,"threshold_uncertainty_score":0.04280335,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01596115045805822,"score_gpt":0.2494707754384581,"score_spread":0.2335096249803998,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}