{"id":"W2952873092","doi":"10.1139/v06-065","title":"Indium(I) iodide promoted cleavage of dialkyl disulfides Application of the Michael addition of thiolate anions to conjugated carbonyl compounds and regioselective ring opening of epoxides","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Council of Scientific and Industrial Research, India","keywords":"Chemistry; Regioselectivity; Iodide; Indium; Nucleophile; Cleavage (geology); Epoxide; Medicinal chemistry; Michael reaction; Conjugated system; Chloride; Sodium iodide; Ring (chemistry); Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002921417,0.000519213,0.0001741611,0.0002386074,0.0001735868,0.0001836639,0.0003489432,0.0002286717,0.001215729],"category_scores_gemma":[0.0001711505,0.0002157786,0.0001889231,0.0001557553,0.0002362459,0.0002813592,0.0002592868,0.0004765586,0.000255604],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003908169,"about_ca_system_score_gemma":0.0003516673,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006529285,"about_ca_topic_score_gemma":0.001750456,"domain_scores_codex":[0.9998779,0.00001482183,0.00001002203,0.00002809343,0.0000363667,0.00003282741],"domain_scores_gemma":[0.9999261,0.00001253252,0.00002062567,0.000007116316,0.00001605465,0.00001753358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003546594,0.000007889715,0.00005561242,0.0000295525,0.000003523858,0.00007627771,0.00003526704,0.00007180671,0.9982753,0.0002648994,0.00003718773,0.001107201],"study_design_scores_gemma":[0.000004423499,0.00005252362,0.0001292793,0.000001113222,0.000002892038,0.00008151335,0.000007035576,0.0001124064,0.9987721,0.00001472262,0.0008197341,0.000002246328],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9787936,0.001487933,0.0110559,0.0001345378,0.0000559749,0.00007539288,0.0001684848,0.0001544765,0.008073603],"genre_scores_gemma":[0.9825786,0.00142219,0.009350779,0.00003623616,0.00001064849,0.00002555818,0.0001922999,0.00002639172,0.006357091],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001215729,"threshold_uncertainty_score":0.004067004,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005075200974502799,"score_gpt":0.1879024506058517,"score_spread":0.1828272496313489,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}