{"id":"W2952873628","doi":"10.1002/chin.200745135","title":"Synthesis of Substituted Triarylpyran (VII) Through an Unexpected Intramolecular Cyclization.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Biological Activity","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Trois-Rivières","funders":"","keywords":"Chemistry; Intramolecular force; Combinatorial chemistry; Stereochemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002942406,0.0001695561,0.0002294903,0.00003043813,0.00005602021,0.00001162314,0.0002319815,0.00027362,0.00007400272],"category_scores_gemma":[0.0005411537,0.0001348013,0.0001227984,0.0001796128,0.0001525533,0.00001626295,0.00005653815,0.00006490891,0.000004228198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001624333,"about_ca_system_score_gemma":0.00003752527,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002798934,"about_ca_topic_score_gemma":0.00001517724,"domain_scores_codex":[0.9989935,0.000003198464,0.0003386738,0.0002674346,0.000137514,0.0002596636],"domain_scores_gemma":[0.9992351,0.00005523957,0.0001530264,0.000357708,0.0001117886,0.00008714727],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002084627,0.0001627934,0.0005911062,0.00001594603,0.00004995692,0.000002477019,0.0000382179,0.000001094992,0.9463089,0.0002437296,0.0001413385,0.05223599],"study_design_scores_gemma":[0.0002695305,0.0000946201,0.005371931,0.00001025197,0.0000241163,0.000007083963,0.0001075835,0.000006640571,0.9864392,0.0000773951,0.007400851,0.0001907416],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9376884,0.0001482058,0.001011272,0.00003088587,0.00006766684,0.0001534268,0.00002192268,0.00003020808,0.06084808],"genre_scores_gemma":[0.9985903,0.0001141421,0.0007543011,0.00008572307,0.0001501738,0.00001135878,0.0001912856,0.00001316764,0.0000895443],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06090197,"threshold_uncertainty_score":0.5497036,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01560498087636753,"score_gpt":0.2617629433464305,"score_spread":0.246157962470063,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}