{"id":"W2952882386","doi":"10.1002/chin.200828029","title":"ChemInform Abstract: Bifunctional Organocatalyst for Methanolytic Desymmetrization of Cyclic Anhydrides: Increasing Enantioselectivity by Catalyst Dilution.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Desymmetrization; Bifunctional; Catalysis; Dilution; Organic chemistry; Combinatorial chemistry; Enantioselective synthesis; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004988679,0.0003862982,0.0006155661,0.0003394602,0.0003463925,0.00003440319,0.0003903284,0.0003389368,0.0004553453],"category_scores_gemma":[0.002094072,0.0003742931,0.0003850446,0.001394056,0.0002249544,0.0006337736,0.00008832588,0.0001933105,0.0000281081],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004177648,"about_ca_system_score_gemma":0.0002452336,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003304332,"about_ca_topic_score_gemma":0.000005594712,"domain_scores_codex":[0.9974997,2.459548e-7,0.0009324459,0.0004487453,0.0006077198,0.0005111381],"domain_scores_gemma":[0.997339,0.0008135487,0.0007291079,0.0005570583,0.0003704164,0.0001908317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002587539,0.0005619999,0.002801279,0.0008598964,0.0006790273,0.000002728956,0.0005014027,0.00000215619,0.3390705,0.0001311178,0.01957636,0.6355548],"study_design_scores_gemma":[0.0006272046,0.00002021582,0.001053232,0.0000546062,0.0002080334,0.00007648303,0.0002619208,0.00009017178,0.9896733,0.00004561159,0.007472516,0.0004167668],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3315051,0.001402149,0.0004353743,0.00008031332,0.0001579903,0.0004584873,0.0007394837,0.0003199348,0.6649011],"genre_scores_gemma":[0.9914801,0.000152582,0.0002098915,0.00002767811,0.0001787739,0.0001017544,0.002309831,0.00005284416,0.005486617],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6599749,"threshold_uncertainty_score":0.9998709,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01554771095982154,"score_gpt":0.2253995965352302,"score_spread":0.2098518855754087,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}