{"id":"W2952892775","doi":"10.1021/ja901187n","title":"Solid-State and Solution Rearrangements of F<sub>3</sub>S≡NXeF<sup>+</sup>Leading to the F<sub>4</sub>S═NXe<sup>+</sup>Cation; Syntheses, HF Solvolyses, and Structural Characterizations of [F<sub>4</sub>S═NXe][AsF<sub>6</sub>] and [F<sub>4</sub>S═NH<sub>2</sub>][AsF<sub>6</sub>]","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Solid-state; X-ray crystallography; Chemical reaction kinetics; Crystallography; Physical chemistry; Chemical kinetics; Diffraction; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000762751,0.0001806348,0.0001221869,0.00006040845,0.0001663353,0.0001237793,0.0001656089,0.0001896711,0.002258972],"category_scores_gemma":[0.0001260663,0.00006782766,0.00008592466,0.00006647799,0.0001691107,0.0001798415,0.0001152868,0.000192889,0.0003146962],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002563875,"about_ca_system_score_gemma":0.0002300915,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001289149,"about_ca_topic_score_gemma":0.002191992,"domain_scores_codex":[0.9999614,0.000003107587,0.000002474406,0.000008605054,0.00001531682,0.000009133218],"domain_scores_gemma":[0.999972,0.000004716229,0.000009213458,0.000002779151,0.000006689638,0.000004637601],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002116777,0.00002811879,0.0003941725,0.00008015768,0.000005915179,0.00009552481,0.00009423398,0.0006568471,0.9901875,0.001235161,0.000334303,0.006676464],"study_design_scores_gemma":[0.00001315652,0.000134339,0.0006539127,0.000003491211,0.000002834796,0.00007906833,0.00003200947,0.0007320211,0.9951728,0.00008808698,0.003082135,0.000006175028],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942207,0.0003220261,0.001973781,0.00003618302,0.00001193761,0.00001411348,0.0002424775,0.00003965045,0.003139102],"genre_scores_gemma":[0.9943777,0.0002113719,0.002506844,0.00001984681,0.000003898108,0.00001347958,0.0003865572,0.00001421684,0.002466134],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002258972,"threshold_uncertainty_score":0.007557034,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008380588343877109,"score_gpt":0.2353738449267661,"score_spread":0.226993256582889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}