{"id":"W2952929440","doi":"10.1021/ja000134c","title":"Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene:  A New Enantioselective Carbon−Heteroatom Bond Forming Process","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":160,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Aminolysis; Enantioselective synthesis; Heteroatom; Rhodium; Catalysis; Organic chemistry; Combinatorial chemistry; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002671333,0.0002486655,0.0007593829,0.0001183425,0.00009843045,0.00003462432,0.0005944568,0.0001083028,0.00008888964],"category_scores_gemma":[0.0002578661,0.0001768415,0.0009229247,0.002810451,0.0003493759,0.0001529945,0.00008285474,0.0004579684,0.000001061883],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002345734,"about_ca_system_score_gemma":0.0001904464,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002524766,"about_ca_topic_score_gemma":0.000002363779,"domain_scores_codex":[0.9979413,0.00002500708,0.0007512341,0.0002763624,0.000659693,0.0003463751],"domain_scores_gemma":[0.9976309,0.0002034226,0.001359464,0.0003210479,0.0002307211,0.0002544362],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002192209,0.0003493473,0.02706816,0.0001142293,0.002381671,0.000003937625,0.00283757,0.00007988579,0.7610202,0.00000579279,0.0008723755,0.2050476],"study_design_scores_gemma":[0.001026048,0.0000335609,0.001389953,0.00004820156,0.0007613517,0.00008022937,0.001180721,0.001108099,0.9935144,0.0001033266,0.0005003944,0.0002537672],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976681,0.0005755698,0.00004919116,0.0003328423,0.00001727433,0.00004610237,0.00001065188,0.00001557328,0.001284712],"genre_scores_gemma":[0.9980859,0.0003089388,0.001033148,0.000131502,0.0001554764,0.000003244085,0.000003560459,0.000027219,0.0002509957],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2324942,"threshold_uncertainty_score":0.7211387,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006757866940407955,"score_gpt":0.2367333233749398,"score_spread":0.2299754564345318,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}