{"id":"W2952948330","doi":"10.1139/v06-177","title":"The efficient and chemoselective MoO<sub>3</sub>-catalyzed oxidation of sulfides to sulfoxides and sulfones with H<sub>2</sub>O<sub>2</sub>","year":2007,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemoselectivity; Chemistry; Catalysis; Hydrogen peroxide; Sulfoxide; Sulfone; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0006192289,0.0004154257,0.0005554133,0.0001294445,0.0004290817,0.0001514241,0.0003349053,0.0003164104,0.0000150193],"category_scores_gemma":[0.0006931376,0.0003257553,0.000170248,0.0004239652,0.0005550021,0.000141534,0.00004987575,0.0005944192,0.000002746753],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004511767,"about_ca_system_score_gemma":0.0007775729,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002483578,"about_ca_topic_score_gemma":0.002548142,"domain_scores_codex":[0.9975539,0.0000202796,0.0008182019,0.0004328578,0.0004553531,0.0007193826],"domain_scores_gemma":[0.9965771,0.0005799831,0.0006456565,0.0003808994,0.0005762738,0.00124005],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002122646,0.00006003397,0.001101209,0.0001657211,0.0001879465,0.00005169209,0.0003476728,0.00003181092,0.9867312,0.000008094685,0.0003446207,0.01075771],"study_design_scores_gemma":[0.0007471014,0.00003130204,0.002674214,0.0003972212,0.0001395517,0.0005809844,0.001178143,0.00001738463,0.9932471,0.00008333547,0.0005119257,0.000391732],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972785,0.001118123,0.000102406,0.0005512958,0.00005809411,0.0001235864,0.00005715232,0.00001839877,0.0006924666],"genre_scores_gemma":[0.9992039,0.0002737154,0.00005967359,0.00004300343,0.0003099366,0.000009434862,0.00001956041,0.00005698522,0.0000238376],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01036598,"threshold_uncertainty_score":0.9999195,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004854899946453423,"score_gpt":0.1869343101066687,"score_spread":0.1820794101602153,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}