{"id":"W2952954186","doi":"10.1002/chin.201649034","title":"ChemInform Abstract: An Organocatalytic Cope Rearrangement.","year":2016,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Cope rearrangement; Organocatalysis; Combinatorial chemistry; Organic chemistry; Catalysis; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001976021,0.0009824267,0.0003606511,0.000770095,0.0004655327,0.0006257664,0.0006631099,0.0007567707,0.01456446],"category_scores_gemma":[0.0003547576,0.0002989199,0.0005306843,0.0005385805,0.0005323883,0.0006487255,0.0009231946,0.00138861,0.004796205],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007040476,"about_ca_system_score_gemma":0.0008714678,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001196526,"about_ca_topic_score_gemma":0.001760005,"domain_scores_codex":[0.9996772,0.00002221497,0.0000116369,0.0000625162,0.0001262751,0.0001001098],"domain_scores_gemma":[0.9999064,0.00001577619,0.00001797158,0.00001553433,0.00001363427,0.00003066032],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001517821,0.000449275,0.00102308,0.002672459,0.0003766198,0.004274898,0.000406546,0.005320753,0.7222246,0.05802317,0.07697265,0.1267382],"study_design_scores_gemma":[0.0004415264,0.00143345,0.002183771,0.0001865302,0.0001366323,0.003478945,0.0001278575,0.003027062,0.7332688,0.004907708,0.2506403,0.000167393],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3001117,0.01317158,0.07179018,0.00502413,0.006649112,0.001638685,0.01213796,0.006067574,0.5834091],"genre_scores_gemma":[0.9040759,0.009834533,0.01816363,0.001947813,0.0004902746,0.000385798,0.003590041,0.0005679837,0.06094406],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01456446,"threshold_uncertainty_score":0.04872298,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0151406561856181,"score_gpt":0.2304895114311048,"score_spread":0.2153488552454867,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}