{"id":"W2952973114","doi":"10.1002/chin.201519189","title":"ChemInform Abstract: A Complete Switch of the Directional Selectivity in the Annulation of 2‐Hydroxybenzaldehydes with Alkynes.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Annulation; Selectivity; Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006624907,0.0001628119,0.0002302748,0.00005310989,0.00005314554,0.00001701274,0.0003196611,0.0001102847,0.0004595342],"category_scores_gemma":[0.00044032,0.0001009587,0.00008798484,0.0005853137,0.0001844949,0.0002253157,0.00006472073,0.0002166848,0.000002823324],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001734144,"about_ca_system_score_gemma":0.0002903129,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002313479,"about_ca_topic_score_gemma":0.0001124051,"domain_scores_codex":[0.9985236,4.33393e-7,0.0004633058,0.0001556609,0.0006847148,0.0001722872],"domain_scores_gemma":[0.9984342,0.0003247134,0.0004266759,0.0004351117,0.0003312657,0.00004805875],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002503413,0.002262035,0.1970031,0.003773984,0.0007621504,0.000008074099,0.04615282,0.002160603,0.3827533,0.007268882,0.06409055,0.2912611],"study_design_scores_gemma":[0.001325906,0.0000242263,0.04532972,0.0001253525,0.00004592361,0.00007029765,0.001334668,0.0004276207,0.927161,0.0006875947,0.02324223,0.0002254765],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.208135,0.00005119335,0.00002351374,0.0002006087,0.00007969185,0.0002036566,0.0000570751,0.00003411444,0.7912152],"genre_scores_gemma":[0.9961058,0.00000232527,0.0001462323,0.00005708508,0.00008196542,0.00003350235,0.00009436914,0.00001346124,0.003465253],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.7879708,"threshold_uncertainty_score":0.5031577,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03813260338721906,"score_gpt":0.2729776392609345,"score_spread":0.2348450358737154,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}