{"id":"W2952990529","doi":"10.1002/chin.200422120","title":"Palladium‐Catalyzed Multicomponent Coupling of Alkynes, Imines, and Acid Chlorides: A Direct and Modular Approach to Pyrrole Synthesis.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Characterization of Pyrroles","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Pyrrole; Palladium; Modular design; Catalysis; Coupling (piping); Combinatorial chemistry; Organic chemistry; Programming language","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001242598,0.0002481873,0.0004131747,0.0000678326,0.00007744759,0.00004759442,0.0001717101,0.0001296162,0.00003851604],"category_scores_gemma":[0.0001684719,0.0002257985,0.00006427083,0.00008582635,0.00008857053,0.0001356375,0.0001144884,0.00007137543,0.00000414967],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000532451,"about_ca_system_score_gemma":0.00003077252,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004275451,"about_ca_topic_score_gemma":0.000001818396,"domain_scores_codex":[0.9988299,1.657667e-7,0.0003868084,0.0003205074,0.000211761,0.0002508319],"domain_scores_gemma":[0.999203,0.0000674523,0.0001598283,0.0003182039,0.0000606812,0.000190869],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006707901,0.00009383905,0.0001668914,0.000470439,0.000061454,0.000001043691,0.0006782025,0.00005317785,0.9856618,0.0000771019,0.00002291809,0.01264602],"study_design_scores_gemma":[0.0005335284,0.000007491705,0.0008934622,0.0002072342,0.00005114714,0.000009655852,0.0005916138,0.0004737092,0.9954971,0.00001111122,0.001459343,0.0002645975],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9820151,0.0004752801,0.00003217012,0.00009797284,0.0000217701,0.0001128407,0.00005030715,0.00006965008,0.01712488],"genre_scores_gemma":[0.9987021,0.0002017507,0.0006253296,0.00002925054,0.0000893454,0.00007428195,0.00006364278,0.00003186928,0.0001823941],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01694249,"threshold_uncertainty_score":0.9207795,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01211070306418528,"score_gpt":0.2051856558719052,"score_spread":0.1930749528077199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}