{"id":"W2952997550","doi":"10.1002/chin.201112102","title":"ChemInform Abstract: Di‐ and Trisubstituted γ‐Lactams via Rh(II)‐Carbenoid Reaction of N‐C<sub>α</sub>‐Branched, N‐Bis(trimethylsilyl)methyl α‐Diazoamides. Synthesis of (.+‐.)‐α‐Allokainic Acid.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"","keywords":"Chemistry; Carbenoid; Trimethylsilyl; Moiety; Stereochemistry; Medicinal chemistry; Catalysis; Rhodium; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007999808,0.0003381198,0.00007863403,0.0001504021,0.000115714,0.0001740736,0.0002440184,0.0001336942,0.003487747],"category_scores_gemma":[0.00008626999,0.00009796918,0.00008459958,0.0001055111,0.0001294499,0.0002329119,0.0001944874,0.0003170052,0.001033411],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003449796,"about_ca_system_score_gemma":0.0002755779,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005934782,"about_ca_topic_score_gemma":0.001297768,"domain_scores_codex":[0.999943,0.000005987299,0.000003592628,0.00001253788,0.00001544724,0.0000193411],"domain_scores_gemma":[0.9999702,0.000003716898,0.000009845715,0.000003643266,0.000004549533,0.000008023388],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002630099,0.00002838146,0.0001637173,0.0001235629,0.0000131308,0.0001770713,0.0000617456,0.0002324787,0.9872963,0.001817939,0.0006129963,0.009209557],"study_design_scores_gemma":[0.00001575777,0.00009728792,0.0004210733,0.000005984421,0.000009120742,0.0001630133,0.00001186337,0.0001678394,0.9927794,0.00007756965,0.006246726,0.000004252844],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9094742,0.004045435,0.01405895,0.0004184817,0.0001813412,0.0001467441,0.0008681097,0.0004771228,0.07032956],"genre_scores_gemma":[0.9849619,0.001427907,0.002844128,0.00007184668,0.000009928814,0.00002814845,0.0003595865,0.00002879336,0.01026778],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003487747,"threshold_uncertainty_score":0.01166767,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01734582686430578,"score_gpt":0.2185479440478415,"score_spread":0.2012021171835357,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}