{"id":"W2953021479","doi":"10.1002/chin.200952062","title":"ChemInform Abstract: Stereoselective Quaternary Center Construction via Atom‐Transfer Radical Cyclization Using Silicon Tethers on Acyclic Precursors.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Montreal Clinical Research Institute","funders":"","keywords":"Chemistry; Stereoselectivity; Center (category theory); Atom (system on chip); Silicon; Transfer (computing); Combinatorial chemistry; Radical cyclization; Stereochemistry; Organic chemistry; Crystallography; Operating system; Catalysis; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002343142,0.0006293188,0.0002622026,0.0004439646,0.00026046,0.0003967442,0.0006638346,0.0003804517,0.01268005],"category_scores_gemma":[0.000214278,0.0002416529,0.0003352814,0.0003494361,0.0002900303,0.0006045563,0.0003762308,0.000857841,0.002954312],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004302972,"about_ca_system_score_gemma":0.0005827611,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000423152,"about_ca_topic_score_gemma":0.0009235184,"domain_scores_codex":[0.9998583,0.00001453228,0.00000945787,0.00003757099,0.00003304384,0.00004722878],"domain_scores_gemma":[0.9999324,0.0000117237,0.0000177377,0.00001214419,0.000009649606,0.00001626635],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004578471,0.0001555654,0.0001515672,0.0006567474,0.00004122862,0.0005353364,0.0001494654,0.001243182,0.9178211,0.01205279,0.01381875,0.0529163],"study_design_scores_gemma":[0.0000697776,0.0006051862,0.0002675558,0.00001571316,0.00002640396,0.0002750443,0.00001916733,0.0009626296,0.968781,0.0006329751,0.02832137,0.00002319798],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6498013,0.007336426,0.1301435,0.001712433,0.002967721,0.0008367226,0.006690983,0.008119828,0.1923911],"genre_scores_gemma":[0.9442617,0.003375948,0.02075579,0.000296459,0.0001355611,0.0001115106,0.002378143,0.0003807144,0.0283041],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01268005,"threshold_uncertainty_score":0.04241902,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01450592600979176,"score_gpt":0.2607247889257566,"score_spread":0.2462188629159649,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}