{"id":"W2953036687","doi":"10.1002/chin.200537049","title":"High‐Yielding Intramolecular Direct Arylation Reactions with Aryl Chlorides.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Intramolecular force; Aryl; Medicinal chemistry; Combinatorial chemistry; Stereochemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008317573,0.0002091255,0.0001842477,0.00005261285,0.0001938537,0.0001008651,0.0001527007,0.0001427452,0.00103351],"category_scores_gemma":[0.00007060492,0.0002023771,0.00008444489,0.0002210341,0.00008736886,0.0004229899,0.0000407377,0.0003033925,0.0001543092],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003813153,"about_ca_system_score_gemma":0.00008082968,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001734522,"about_ca_topic_score_gemma":0.00003237571,"domain_scores_codex":[0.9988555,3.248686e-9,0.000310859,0.0002710757,0.0002533232,0.0003092305],"domain_scores_gemma":[0.999051,0.00008046492,0.0001569586,0.0005012486,0.00008776844,0.0001225655],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000753791,0.0001120425,0.0002378188,0.0001544813,0.0001550154,0.00001621376,0.0003788249,0.0005801449,0.9308727,0.0004185143,0.001856667,0.06514222],"study_design_scores_gemma":[0.0004031211,0.00000765001,0.0001463989,0.0001186455,0.00006128089,0.00008270622,0.0001716328,0.000463711,0.9799255,0.00003050504,0.01832716,0.0002616469],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8922474,0.00005442294,0.00001461764,0.0002571857,0.00008943117,0.00006802507,0.0000163012,0.0003544205,0.1068981],"genre_scores_gemma":[0.9912903,0.00003205999,0.0001071732,0.00003441801,0.0004649796,0.00004450336,0.0002279081,0.00003891312,0.007759802],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09913833,"threshold_uncertainty_score":0.9998797,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007886361477326874,"score_gpt":0.2267014077333061,"score_spread":0.2188150462559793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}