{"id":"W2953036687","doi":"10.1002/chin.200537049","title":"High‐Yielding Intramolecular Direct Arylation Reactions with Aryl Chlorides.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Intramolecular force; Aryl; Medicinal chemistry; Combinatorial chemistry; Stereochemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005163582,0.001078019,0.0004161621,0.0003774801,0.0003776487,0.0003487407,0.0009667971,0.0004665843,0.009021665],"category_scores_gemma":[0.0004474027,0.0003534603,0.0003298057,0.0004919174,0.0002599102,0.0006534969,0.0007639229,0.001559635,0.004589577],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004379101,"about_ca_system_score_gemma":0.0005460857,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001119663,"about_ca_topic_score_gemma":0.0027921,"domain_scores_codex":[0.9996544,0.00004639505,0.0000209816,0.00007298618,0.00008333629,0.0001219442],"domain_scores_gemma":[0.9999142,0.00001930529,0.00001440191,0.00001563262,0.00001932028,0.00001713561],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004864039,0.0003150323,0.0002956399,0.0009664702,0.0001500208,0.0007289911,0.0003926576,0.001091851,0.9177446,0.004839643,0.01212008,0.06086864],"study_design_scores_gemma":[0.0001471921,0.0005006129,0.0007498416,0.00003554577,0.00009336518,0.0005770036,0.00004267665,0.001000029,0.9537961,0.0004795031,0.04253144,0.00004670541],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5774197,0.02742719,0.1755289,0.001905412,0.001194424,0.0007072196,0.003902084,0.003591128,0.2083239],"genre_scores_gemma":[0.9420461,0.01142238,0.01819008,0.0003501843,0.0001211814,0.0002031548,0.001684531,0.0002564341,0.02572594],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009021665,"threshold_uncertainty_score":0.03018051,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007886361477326874,"score_gpt":0.2267014077333061,"score_spread":0.2188150462559793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}