{"id":"W2953040138","doi":"10.1002/adsc.200900710","title":"Bismuth Triflate‐Catalyzed Addition of Allylsilanes to <i>N</i>‐Alkoxycarbonylamino Sulfones: Convenient Access to 3‐Cbz‐Protected Cyclohexenylamines","year":2009,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Trifluoromethanesulfonate; Chemistry; Bismuth; Catalysis; Ring-closing metathesis; Metathesis; Medicinal chemistry; Salt metathesis reaction; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005357613,0.000817184,0.001508267,0.0004688255,0.0001720264,0.0001081715,0.001614395,0.0003624637,0.001687848],"category_scores_gemma":[0.004554664,0.0008308241,0.0004912224,0.001943851,0.0001275229,0.0003988724,0.0002837784,0.0002797419,0.0000923589],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002950454,"about_ca_system_score_gemma":0.0001540309,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001335984,"about_ca_topic_score_gemma":0.00003491862,"domain_scores_codex":[0.9951493,0.0001148771,0.001414389,0.001473664,0.0009409054,0.0009068761],"domain_scores_gemma":[0.9949217,0.001175176,0.0006620027,0.002243965,0.0004160512,0.0005811296],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000387741,0.0003210376,0.0001081646,0.0001540872,0.0002002132,0.00002378441,0.0003840642,0.0002558365,0.8909902,0.0000108942,0.000152857,0.1070111],"study_design_scores_gemma":[0.0006752426,0.00005390789,0.0009186476,0.0004048283,0.000493557,0.00003288432,0.0003663319,0.00005498536,0.9923579,0.0001830505,0.003551833,0.0009068646],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892294,0.0002478747,0.003347214,0.001437202,0.0001479056,0.0006188989,0.0004956849,0.000473661,0.004002195],"genre_scores_gemma":[0.984346,0.00006801488,0.01376627,0.0002217719,0.0002231765,0.0004278453,0.0003052737,0.0001161466,0.0005255138],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1061043,"threshold_uncertainty_score":0.9994143,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01518392349473357,"score_gpt":0.2847025116321333,"score_spread":0.2695185881373997,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}