{"id":"W2953046871","doi":"10.1021/ic400805c","title":"Synthesis of [N(CH<sub>3</sub>)<sub>4</sub>]<sub>2</sub>O<sub>3</sub>SOSO<sub>2</sub>(s) and [N(CH<sub>3</sub>)<sub>4</sub>]<sub>2</sub>[(O<sub>2</sub>SO)<sub>2</sub>SO<sub>2</sub>]·SO<sub>2</sub>(s) Containing (SO<sub>4</sub>)(SO<sub>2</sub>)<sub><i>x</i></sub><sup>2–</sup><i>x</i>= 1, 2, Members of a New Class of Sulfur Oxydianions","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Solid-state spectroscopy and crystallography","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Atlantic Hydrogen (Canada); University of New Brunswick","funders":"","keywords":"Chemistry; Raman spectroscopy; Sulfur; Crystallography; Infrared spectroscopy; Infrared; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity"],"category_scores_codex":[0.02106658,0.03375029,0.03391253,0.01490107,0.01555439,0.01240987,0.0262616,0.02363336,0.0008229638],"category_scores_gemma":[0.01363672,0.03972943,0.01943868,0.03298521,0.02604397,0.01815988,0.0167203,0.02768065,0.007955943],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.01462152,"about_ca_system_score_gemma":0.02268909,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001447711,"about_ca_topic_score_gemma":0.008909318,"domain_scores_codex":[0.8633666,0.01114665,0.0343815,0.03247007,0.02441462,0.03422055],"domain_scores_gemma":[0.8938515,0.014845,0.02896502,0.02734228,0.01340001,0.02159614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01091057,0.01225825,0.002999367,0.01192791,0.01155876,0.004674508,0.009245631,0.003293735,0.8534408,0.0007893149,0.038467,0.04043421],"study_design_scores_gemma":[0.03127627,0.005463274,0.003851234,0.01211629,0.01397541,0.006618558,0.01063611,0.002955412,0.8713689,0.004494687,0.003612544,0.03363133],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9150887,0.01275568,0.002489151,0.003615696,0.01200276,0.02298974,0.01845707,0.01067675,0.001924446],"genre_scores_gemma":[0.9026753,0.04788066,0.001127052,0.006055977,0.01122162,0.009712311,0.01012495,0.01112443,0.00007772347],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03512498,"threshold_uncertainty_score":0.9962642,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00785076367907621,"score_gpt":0.2128691512936228,"score_spread":0.2050183876145466,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}