{"id":"W2953072596","doi":"10.1021/om060942y","title":"Rhodium N-Heterocyclic Carbene Carboxylato Complexes:  Synthesis, Structure Determination, and Catalytic Activity in the Hydroformylation of Alkenes","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Hydroformylation; Chemistry; Rhodium; Carbene; Regioselectivity; Isomerization; Catalysis; Aryl; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003287256,0.0003323138,0.0004474693,0.0001165803,0.0001170745,0.00004662978,0.0004818603,0.0002897269,0.0003370887],"category_scores_gemma":[0.0002211805,0.0002784851,0.00009403569,0.000404959,0.0002311902,0.0002507188,0.0001501388,0.0003383117,0.000002396758],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001779197,"about_ca_system_score_gemma":0.00004129032,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001683375,"about_ca_topic_score_gemma":0.0002891904,"domain_scores_codex":[0.9981338,0.00002881979,0.0005737329,0.0004348497,0.0004216927,0.0004070914],"domain_scores_gemma":[0.9983358,0.0004984571,0.0003216991,0.000686593,0.00006423595,0.00009320092],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003182355,0.00008146829,0.00818912,0.0002780713,0.00003777628,0.000007983814,0.0007875303,0.0000040992,0.9845606,0.0000831969,0.00000682653,0.005931491],"study_design_scores_gemma":[0.0004005871,0.00001379177,0.01809995,0.00004641143,0.00009323993,0.0001100036,0.0006341199,0.0002037435,0.9793609,0.0002430874,0.0004942004,0.0002999242],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966971,0.0003127072,0.0001153232,0.0001014578,0.00007372707,0.0001195216,0.00007030948,0.00004022501,0.002469665],"genre_scores_gemma":[0.9993867,0.00010215,0.0001266704,0.00005162254,0.000152389,0.00000670296,0.00004863771,0.00004648675,0.00007861911],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009910831,"threshold_uncertainty_score":0.9999667,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009460697814157587,"score_gpt":0.2385720890368822,"score_spread":0.2291113912227246,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}