{"id":"W2953119430","doi":"10.1002/chin.201551068","title":"ChemInform Abstract: Palladium‐Catalyzed 1,4‐Addition of Terminal Alkynes to Acrolein.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Acetone; Acrolein; Catalysis; Palladium; Solvent; Terminal (telecommunication); Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001326601,0.0006775741,0.0001307462,0.0004664802,0.0002337354,0.0003323928,0.0004011652,0.000282751,0.0113921],"category_scores_gemma":[0.0001678703,0.0002070531,0.000152274,0.0002930684,0.000182839,0.0004376124,0.0004772625,0.000712699,0.00460049],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004259278,"about_ca_system_score_gemma":0.0004791522,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005401786,"about_ca_topic_score_gemma":0.001292521,"domain_scores_codex":[0.9998899,0.00001092693,0.000005947055,0.00003056004,0.00003644678,0.00002618607],"domain_scores_gemma":[0.9999666,0.000005167027,0.000008280163,0.000005791632,0.000006177703,0.00000804268],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000328803,0.0001285826,0.0002262888,0.0004966638,0.00003896186,0.0005089563,0.00008355798,0.0008907397,0.9263717,0.006118401,0.008840916,0.05596648],"study_design_scores_gemma":[0.0000577707,0.0001433919,0.0005280164,0.00002626275,0.00001854701,0.0002724457,0.00001667364,0.0007270594,0.9551997,0.000397643,0.04260148,0.00001101374],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5319787,0.008312712,0.1160907,0.001582449,0.001244624,0.0007502265,0.006236253,0.008589987,0.3252144],"genre_scores_gemma":[0.9356419,0.004844526,0.01939212,0.0001945941,0.00006597536,0.0001166173,0.002730152,0.0002670522,0.03674699],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0113921,"threshold_uncertainty_score":0.03811032,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02248445821118451,"score_gpt":0.2640030836557014,"score_spread":0.2415186254445169,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}